Literature DB >> 23125982

Catalytic coupling of nitriles with amines to selectively form imines under mild hydrogen pressure.

Dipankar Srimani1, Moran Feller, Yehoshoa Ben-David, David Milstein.   

Abstract

Imines are selectively formed by coupling of nitriles and amines under mild hydrogen pressure. The reaction is catalyzed by a bipyridine-based PNN Ru(II) pincer complex and proceeds under mild, neutral conditions at 4 bar of H(2).

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Year:  2012        PMID： 23125982     DOI： 10.1039/c2cc36639h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Heterolytic Cleavage of Dihydrogen by an Iron(II) PNP Pincer Complex via Metal-Ligand Cooperation.

Authors:  Bernhard Bichler; Christian Holzhacker; Berthold Stöger; Michael Puchberger; Luis F Veiros; Karl Kirchner
Journal:  Organometallics       Date:  2013-07-26       Impact factor: 3.876

2.  On the Unique Reactivity of Pd(OAc)2 with Organic Azides: Expedient Synthesis of Nitriles and Imines.

Authors:  Laura Martínez-Sarti; Silvia Díez-González
Journal:  ChemCatChem       Date:  2013-04-10       Impact factor: 5.686

3.  Nickel-Catalyzed Transfer Hydrogenation of Benzonitriles with 2-Propanol and 1,4-Butanediol as the Hydrogen Source.

Authors:  Jorge A Garduño; Juventino J García
Journal:  ACS Omega       Date:  2017-05-26

4.  Facile Amine Termination of Nanodiamond Particles and Their Surface Reaction Dynamics.

Authors:  Laia Gines; Soumen Mandal; Chang-You Song; Oliver A Williams; Micahella N Sarmiento; Chia-Liang Cheng
Journal:  ACS Omega       Date:  2019-10-01

5.  Facile Conversion of Aryl Amines Having No α-Methylene to Aryl Nitriles.

Authors:  Shyamkanhai S Moirangthem; Dini Ahanthem; Sanatombi D Khongbantabam; Warjeet S Laitonjam
Journal:  ACS Omega       Date:  2022-08-22

6.  Pd-CuFe Catalyst for Transfer Hydrogenation of Nitriles: Controllable Selectivity to Primary Amines and Secondary Amines.

Authors:  Lei Liu; Yuhong Liu; Yongjian Ai; Jifan Li; Junjie Zhou; Zhibo Fan; Hongjie Bao; Ruihang Jiang; Zenan Hu; Jingting Wang; Ke Jing; Yue Wang; Qionglin Liang; Hongbin Sun
Journal:  iScience       Date:  2018-09-19
  6 in total

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