Literature DB >> 23125655

2,2'-{[(2,2'-Dieth-oxy-1,1'-binaphthalene-6,6'-di-yl)bis-(4,1-phenyl-ene)]bis-(methan-ylyl-idene)}dimalononitrile.

Shikun Chen1.   

Abstract

The title compound, C(44)H(30)N(4)O(2), was prepared from 6,6'-dibromo-2,2'-dieth-oxy-1,1'-binaphthalene through a coupling reaction with 4-(4,4,5,5-tetra-methyl-1,3,2-dioxaborolan-2-yl)benzaldehyde followed by a Knoevenagel reaction with malononitrile. The dihedral angle between the symmetry-related naphthalene ring systems is 68.82 (8)° while the dihedral angle between the the naphthalene ring system and the adjacent benzene ring is 16.92 (7)°. Four symmetry-independent mol-ecules which are linked by inter-molecular C-H⋯π inter-action generate the packing motif in the crystal structure. One of the CN groups is disordered over two sets of sites in a 0.60 (2):0.40 (2) ratio.

Entities:  

Year:  2012        PMID: 23125655      PMCID: PMC3470211          DOI: 10.1107/S1600536812037282

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


  3 in total

Review 1.  BINOL: a versatile chiral reagent.

Authors:  Jean Michel Brunel
Journal:  Chem Rev       Date:  2005-03       Impact factor: 60.622

2.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

3.  Asymmetric allylboration of ketones catalyzed by chiral diols.

Authors:  Sha Lou; Philip N Moquist; Scott E Schaus
Journal:  J Am Chem Soc       Date:  2006-10-04       Impact factor: 15.419

  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.