(4-Meth-oxy-phen-yl)(4-methyl-cyclo-hex-yl)methanone.

The title compound, C(15)H(20)O(2), crystallizes with two independent mol-ecules of similar geometry in the asymmetric unit. The cyclo-hexyl ring adopts a chair conformation in each mol-ecule. In the crystal, mol-ecules related by translation are linked into chains along the a axis via weak C-H⋯O inter-actions.

Related literature

For the anti­hyperglycemic activity of SGLT2 inhibitors, see: Shao et al. (2011 ▶); Zhao et al. (2011 ▶). For related structures, see: Meng et al. (2012 ▶); Wang et al. (2011 ▶).

Experimental

Crystal data

C15H20O2

M = 232.31

Triclinic,

a = 5.7003 (18) Å

b = 7.279 (2) Å

c = 30.76 (1) Å

α = 96.700 (9)°

β = 94.380 (16)°

γ = 93.332 (12)°

V = 1261.0 (7) Å3

Z = 4

Mo Kα radiation

μ = 0.08 mm−1

T = 113 K

0.20 × 0.18 × 0.12 mm

Data collection

Rigaku Saturn CCD area-detector diffractometer

Absorption correction: multi-scan (CrystalClear; Rigaku/MSC, 2009 ▶) T min = 0.984, T max = 0.991

12908 measured reflections

5924 independent reflections

3739 reflections with I > 2σ(I)

R int = 0.038

Refinement

R[F 2 > 2σ(F 2)] = 0.043

wR(F 2) = 0.120

S = 1.03

5924 reflections

311 parameters

H-atom parameters constrained

Δρmax = 0.35 e Å−3

Δρmin = −0.18 e Å−3

Data collection: CrystalClear (Rigaku/MSC, 2009 ▶); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536812037373/cv5337sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536812037373/cv5337Isup2.hkl

Supplementary material file. DOI: 10.1107/S1600536812037373/cv5337Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C15H20O2	Z = 4
Mr = 232.31	F(000) = 504
Triclinic, P1	Dx = 1.224 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 5.7003 (18) Å	Cell parameters from 4144 reflections
b = 7.279 (2) Å	θ = 2.0–27.9°
c = 30.76 (1) Å	µ = 0.08 mm−1
α = 96.700 (9)°	T = 113 K
β = 94.380 (16)°	Prism, colourless
γ = 93.332 (12)°	0.20 × 0.18 × 0.12 mm
V = 1261.0 (7) Å3

Rigaku Saturn CCD area-detector diffractometer	5924 independent reflections
Radiation source: rotating anode	3739 reflections with I > 2σ(I)
Multilayer monochromator	Rint = 0.038
Detector resolution: 14.63 pixels mm-1	θmax = 27.9°, θmin = 2.0°
ω and φ scans	h = −7→7
Absorption correction: multi-scan (CrystalClear; Rigaku/MSC, 2009)	k = −9→9
Tmin = 0.984, Tmax = 0.991	l = −39→40
12908 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.043	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.120	H-atom parameters constrained
S = 1.03	w = 1/[σ2(Fo2) + (0.0506P)2] where P = (Fo2 + 2Fc2)/3
5924 reflections	(Δ/σ)max = 0.004
311 parameters	Δρmax = 0.35 e Å−3
0 restraints	Δρmin = −0.18 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
O1	0.19664 (16)	1.11167 (12)	0.33482 (3)	0.0263 (2)
O2	0.46796 (15)	0.82156 (13)	0.14498 (3)	0.0305 (2)
O3	0.77830 (16)	0.33602 (12)	0.17072 (3)	0.0275 (2)
O4	0.52284 (16)	0.73059 (14)	0.35409 (3)	0.0334 (3)
C1	0.4001 (2)	1.19400 (18)	0.36164 (4)	0.0295 (3)
H1A	0.5278	1.1096	0.3598	0.044*
H1B	0.3614	1.2175	0.3922	0.044*
H1C	0.4506	1.3113	0.3513	0.044*
C2	0.2251 (2)	1.05419 (16)	0.29179 (4)	0.0209 (3)
C3	0.4298 (2)	1.08989 (16)	0.27130 (4)	0.0218 (3)
H3	0.5619	1.1598	0.2870	0.026*
C4	0.4368 (2)	1.02131 (16)	0.22748 (4)	0.0212 (3)
H4	0.5772	1.0428	0.2135	0.025*
C5	0.2447 (2)	0.92202 (16)	0.20324 (4)	0.0192 (3)
C6	0.0383 (2)	0.89343 (16)	0.22415 (4)	0.0205 (3)
H6	−0.0971	0.8298	0.2080	0.025*
C7	0.0302 (2)	0.95706 (16)	0.26805 (4)	0.0213 (3)
H7	−0.1094	0.9343	0.2821	0.026*
C8	0.2704 (2)	0.84618 (17)	0.15690 (4)	0.0219 (3)
C9	0.0566 (2)	0.80827 (17)	0.12401 (4)	0.0220 (3)
H9	−0.0875	0.7917	0.1401	0.026*
C10	0.0752 (2)	0.63558 (17)	0.09157 (4)	0.0272 (3)
H10A	0.0743	0.5251	0.1075	0.033*
H10B	0.2267	0.6453	0.0780	0.033*
C11	−0.1284 (2)	0.61157 (18)	0.05559 (4)	0.0283 (3)
H11A	−0.1074	0.5011	0.0346	0.034*
H11B	−0.2787	0.5904	0.0690	0.034*
C12	−0.1415 (2)	0.78128 (18)	0.03088 (4)	0.0258 (3)
H12	0.0095	0.7978	0.0168	0.031*
C13	−0.1635 (2)	0.95325 (18)	0.06335 (4)	0.0267 (3)
H13A	−0.3154	0.9416	0.0767	0.032*
H13B	−0.1645	1.0637	0.0474	0.032*
C14	0.0378 (2)	0.98096 (17)	0.09963 (4)	0.0259 (3)
H14A	0.0112	1.0894	0.1208	0.031*
H14B	0.1881	1.0071	0.0867	0.031*
C15	−0.3433 (3)	0.7554 (2)	−0.00528 (4)	0.0344 (3)
H15A	−0.4931	0.7358	0.0077	0.052*
H15B	−0.3195	0.6475	−0.0263	0.052*
H15C	−0.3470	0.8664	−0.0205	0.052*
C16	0.5868 (3)	0.3403 (2)	0.13812 (4)	0.0324 (3)
H16A	0.4446	0.2788	0.1474	0.049*
H16B	0.6262	0.2756	0.1101	0.049*
H16C	0.5582	0.4693	0.1345	0.049*
C17	0.7511 (2)	0.41843 (16)	0.21210 (4)	0.0213 (3)
C18	0.5547 (2)	0.51267 (16)	0.22355 (4)	0.0215 (3)
H18	0.4286	0.5234	0.2021	0.026*
C19	0.5460 (2)	0.59047 (16)	0.26667 (4)	0.0214 (3)
H19	0.4111	0.6529	0.2747	0.026*
C20	0.7298 (2)	0.57948 (16)	0.29851 (4)	0.0195 (3)
C21	0.9266 (2)	0.48535 (16)	0.28615 (4)	0.0214 (3)
H21	1.0549	0.4774	0.3073	0.026*
C22	0.9355 (2)	0.40431 (16)	0.24356 (4)	0.0219 (3)
H22	1.0681	0.3386	0.2357	0.026*
C23	0.7117 (2)	0.67370 (17)	0.34374 (4)	0.0223 (3)
C24	0.9260 (2)	0.69855 (17)	0.37672 (4)	0.0216 (3)
H24	1.0706	0.7109	0.3605	0.026*
C25	0.9183 (2)	0.87238 (17)	0.40970 (4)	0.0242 (3)
H25A	0.9196	0.9833	0.3939	0.029*
H25B	0.7700	0.8658	0.4244	0.029*
C26	1.1281 (2)	0.89120 (17)	0.44422 (4)	0.0251 (3)
H26A	1.1156	1.0027	0.4654	0.030*
H26B	1.2757	0.9082	0.4297	0.030*
C27	1.1396 (2)	0.72105 (18)	0.46893 (4)	0.0252 (3)
H27	0.9918	0.7093	0.4842	0.030*
C28	1.1465 (2)	0.54731 (17)	0.43608 (4)	0.0250 (3)
H28A	1.2954	0.5536	0.4216	0.030*
H28B	1.1451	0.4369	0.4521	0.030*
C29	0.9384 (2)	0.52528 (17)	0.40108 (4)	0.0244 (3)
H29A	0.7900	0.5053	0.4151	0.029*
H29B	0.9552	0.4151	0.3797	0.029*
C30	1.3480 (2)	0.74087 (19)	0.50368 (4)	0.0329 (3)
H30A	1.3497	0.6296	0.5188	0.049*
H30B	1.3330	0.8497	0.5250	0.049*
H30C	1.4951	0.7561	0.4896	0.049*

	U11	U22	U33	U12	U13	U23
O1	0.0278 (5)	0.0285 (5)	0.0217 (5)	0.0011 (4)	0.0032 (4)	−0.0006 (4)
O2	0.0202 (5)	0.0442 (6)	0.0272 (5)	0.0045 (4)	0.0047 (4)	0.0015 (4)
O3	0.0290 (5)	0.0311 (5)	0.0217 (5)	0.0059 (4)	0.0004 (4)	−0.0002 (4)
O4	0.0217 (5)	0.0480 (6)	0.0301 (6)	0.0073 (5)	0.0046 (4)	−0.0009 (5)
C1	0.0333 (8)	0.0294 (7)	0.0232 (7)	0.0005 (6)	−0.0047 (6)	−0.0016 (6)
C2	0.0240 (7)	0.0176 (6)	0.0220 (7)	0.0046 (5)	0.0028 (6)	0.0040 (5)
C3	0.0187 (7)	0.0193 (6)	0.0270 (7)	−0.0002 (5)	−0.0017 (5)	0.0042 (5)
C4	0.0172 (7)	0.0214 (6)	0.0259 (7)	0.0016 (5)	0.0025 (5)	0.0058 (5)
C5	0.0175 (7)	0.0183 (6)	0.0227 (7)	0.0032 (5)	0.0009 (5)	0.0058 (5)
C6	0.0173 (7)	0.0178 (6)	0.0263 (7)	0.0000 (5)	0.0012 (5)	0.0035 (5)
C7	0.0197 (7)	0.0195 (6)	0.0256 (7)	0.0000 (5)	0.0050 (5)	0.0055 (5)
C8	0.0217 (7)	0.0223 (6)	0.0224 (7)	0.0027 (5)	0.0018 (6)	0.0053 (5)
C9	0.0182 (7)	0.0279 (7)	0.0197 (7)	0.0013 (5)	0.0024 (5)	0.0022 (5)
C10	0.0285 (8)	0.0238 (6)	0.0288 (8)	0.0031 (6)	−0.0009 (6)	0.0025 (6)
C11	0.0295 (8)	0.0265 (7)	0.0269 (8)	0.0009 (6)	−0.0016 (6)	−0.0018 (6)
C12	0.0243 (7)	0.0334 (7)	0.0189 (7)	0.0012 (6)	0.0026 (6)	0.0001 (6)
C13	0.0281 (8)	0.0282 (7)	0.0241 (7)	0.0049 (6)	0.0000 (6)	0.0043 (6)
C14	0.0267 (7)	0.0245 (7)	0.0253 (7)	0.0021 (6)	−0.0017 (6)	0.0000 (6)
C15	0.0362 (9)	0.0414 (8)	0.0234 (8)	0.0020 (7)	−0.0038 (6)	−0.0001 (6)
C16	0.0377 (9)	0.0345 (8)	0.0233 (8)	0.0044 (7)	−0.0038 (6)	−0.0001 (6)
C17	0.0237 (7)	0.0187 (6)	0.0214 (7)	−0.0014 (5)	0.0034 (6)	0.0032 (5)
C18	0.0194 (7)	0.0209 (6)	0.0240 (7)	−0.0002 (5)	−0.0025 (5)	0.0057 (5)
C19	0.0177 (7)	0.0194 (6)	0.0279 (7)	0.0008 (5)	0.0035 (6)	0.0050 (5)
C20	0.0174 (6)	0.0188 (6)	0.0224 (7)	−0.0012 (5)	0.0022 (5)	0.0047 (5)
C21	0.0184 (7)	0.0227 (6)	0.0236 (7)	0.0008 (5)	0.0004 (5)	0.0064 (5)
C22	0.0201 (7)	0.0195 (6)	0.0273 (7)	0.0030 (5)	0.0050 (6)	0.0052 (5)
C23	0.0205 (7)	0.0226 (6)	0.0247 (7)	0.0009 (5)	0.0046 (6)	0.0055 (5)
C24	0.0196 (7)	0.0244 (6)	0.0209 (7)	0.0009 (5)	0.0041 (5)	0.0022 (5)
C25	0.0244 (7)	0.0235 (6)	0.0247 (7)	0.0026 (5)	0.0034 (6)	0.0019 (5)
C26	0.0255 (7)	0.0250 (6)	0.0237 (7)	0.0001 (5)	0.0023 (6)	−0.0015 (5)
C27	0.0245 (7)	0.0298 (7)	0.0208 (7)	0.0002 (6)	0.0033 (6)	0.0012 (6)
C28	0.0275 (8)	0.0251 (6)	0.0224 (7)	0.0028 (6)	0.0005 (6)	0.0033 (5)
C29	0.0260 (7)	0.0239 (6)	0.0226 (7)	−0.0002 (5)	0.0013 (6)	0.0012 (5)
C30	0.0342 (9)	0.0367 (8)	0.0262 (8)	0.0037 (7)	−0.0020 (6)	−0.0006 (6)

O1—C2	1.3658 (15)	C15—H15A	0.9800
O1—C1	1.4289 (16)	C15—H15B	0.9800
O2—C8	1.2273 (14)	C15—H15C	0.9800
O3—C17	1.3663 (15)	C16—H16A	0.9800
O3—C16	1.4290 (16)	C16—H16B	0.9800
O4—C23	1.2269 (14)	C16—H16C	0.9800
C1—H1A	0.9800	C17—C22	1.3898 (18)
C1—H1B	0.9800	C17—C18	1.3936 (17)
C1—H1C	0.9800	C18—C19	1.3860 (17)
C2—C7	1.3897 (18)	C18—H18	0.9500
C2—C3	1.3935 (17)	C19—C20	1.3908 (17)
C3—C4	1.3863 (17)	C19—H19	0.9500
C3—H3	0.9500	C20—C21	1.4022 (17)
C4—C5	1.3910 (17)	C20—C23	1.4915 (17)
C4—H4	0.9500	C21—C22	1.3785 (17)
C5—C6	1.4000 (16)	C21—H21	0.9500
C5—C8	1.4886 (17)	C22—H22	0.9500
C6—C7	1.3806 (17)	C23—C24	1.5152 (18)
C6—H6	0.9500	C24—C25	1.5317 (16)
C7—H7	0.9500	C24—C29	1.5427 (17)
C8—C9	1.5142 (18)	C24—H24	1.0000
C9—C10	1.5251 (17)	C25—C26	1.5264 (18)
C9—C14	1.5418 (17)	C25—H25A	0.9900
C9—H9	1.0000	C25—H25B	0.9900
C10—C11	1.5290 (18)	C26—C27	1.5289 (17)
C10—H10A	0.9900	C26—H26A	0.9900
C10—H10B	0.9900	C26—H26B	0.9900
C11—C12	1.5266 (18)	C27—C30	1.5244 (18)
C11—H11A	0.9900	C27—C28	1.5283 (17)
C11—H11B	0.9900	C27—H27	1.0000
C12—C15	1.5252 (18)	C28—C29	1.5277 (17)
C12—C13	1.5251 (18)	C28—H28A	0.9900
C12—H12	1.0000	C28—H28B	0.9900
C13—C14	1.5256 (18)	C29—H29A	0.9900
C13—H13A	0.9900	C29—H29B	0.9900
C13—H13B	0.9900	C30—H30A	0.9800
C14—H14A	0.9900	C30—H30B	0.9800
C14—H14B	0.9900	C30—H30C	0.9800
C2—O1—C1	117.19 (10)	H15B—C15—H15C	109.5
C17—O3—C16	117.13 (10)	O3—C16—H16A	109.5
O1—C1—H1A	109.5	O3—C16—H16B	109.5
O1—C1—H1B	109.5	H16A—C16—H16B	109.5
H1A—C1—H1B	109.5	O3—C16—H16C	109.5
O1—C1—H1C	109.5	H16A—C16—H16C	109.5
H1A—C1—H1C	109.5	H16B—C16—H16C	109.5
H1B—C1—H1C	109.5	O3—C17—C22	115.81 (11)
O1—C2—C7	115.38 (11)	O3—C17—C18	124.01 (12)
O1—C2—C3	124.43 (12)	C22—C17—C18	120.19 (12)
C7—C2—C3	120.18 (12)	C19—C18—C17	118.95 (12)
C4—C3—C2	118.62 (12)	C19—C18—H18	120.5
C4—C3—H3	120.7	C17—C18—H18	120.5
C2—C3—H3	120.7	C18—C19—C20	121.69 (11)
C3—C4—C5	122.11 (11)	C18—C19—H19	119.2
C3—C4—H4	118.9	C20—C19—H19	119.2
C5—C4—H4	118.9	C19—C20—C21	118.35 (12)
C4—C5—C6	118.18 (12)	C19—C20—C23	118.46 (11)
C4—C5—C8	118.67 (11)	C21—C20—C23	123.16 (12)
C6—C5—C8	123.13 (12)	C22—C21—C20	120.54 (12)
C7—C6—C5	120.43 (12)	C22—C21—H21	119.7
C7—C6—H6	119.8	C20—C21—H21	119.7
C5—C6—H6	119.8	C21—C22—C17	120.26 (11)
C6—C7—C2	120.42 (11)	C21—C22—H22	119.9
C6—C7—H7	119.8	C17—C22—H22	119.9
C2—C7—H7	119.8	O4—C23—C20	119.73 (12)
O2—C8—C5	119.42 (12)	O4—C23—C24	120.28 (12)
O2—C8—C9	119.92 (11)	C20—C23—C24	119.99 (10)
C5—C8—C9	120.59 (10)	C23—C24—C25	111.55 (10)
C8—C9—C10	112.24 (10)	C23—C24—C29	109.11 (11)
C8—C9—C14	106.83 (11)	C25—C24—C29	110.09 (10)
C10—C9—C14	110.54 (11)	C23—C24—H24	108.7
C8—C9—H9	109.1	C25—C24—H24	108.7
C10—C9—H9	109.1	C29—C24—H24	108.7
C14—C9—H9	109.1	C26—C25—C24	111.27 (10)
C9—C10—C11	111.49 (10)	C26—C25—H25A	109.4
C9—C10—H10A	109.3	C24—C25—H25A	109.4
C11—C10—H10A	109.3	C26—C25—H25B	109.4
C9—C10—H10B	109.3	C24—C25—H25B	109.4
C11—C10—H10B	109.3	H25A—C25—H25B	108.0
H10A—C10—H10B	108.0	C25—C26—C27	111.83 (11)
C12—C11—C10	111.75 (11)	C25—C26—H26A	109.2
C12—C11—H11A	109.3	C27—C26—H26A	109.3
C10—C11—H11A	109.3	C25—C26—H26B	109.3
C12—C11—H11B	109.3	C27—C26—H26B	109.3
C10—C11—H11B	109.3	H26A—C26—H26B	107.9
H11A—C11—H11B	107.9	C30—C27—C28	111.83 (10)
C15—C12—C13	111.66 (11)	C30—C27—C26	111.76 (11)
C15—C12—C11	111.45 (12)	C28—C27—C26	109.44 (11)
C13—C12—C11	109.48 (11)	C30—C27—H27	107.9
C15—C12—H12	108.0	C28—C27—H27	107.9
C13—C12—H12	108.0	C26—C27—H27	107.9
C11—C12—H12	108.0	C29—C28—C27	112.45 (10)
C12—C13—C14	112.18 (10)	C29—C28—H28A	109.1
C12—C13—H13A	109.2	C27—C28—H28A	109.1
C14—C13—H13A	109.2	C29—C28—H28B	109.1
C12—C13—H13B	109.2	C27—C28—H28B	109.1
C14—C13—H13B	109.2	H28A—C28—H28B	107.8
H13A—C13—H13B	107.9	C28—C29—C24	111.02 (11)
C13—C14—C9	111.44 (11)	C28—C29—H29A	109.4
C13—C14—H14A	109.3	C24—C29—H29A	109.4
C9—C14—H14A	109.3	C28—C29—H29B	109.4
C13—C14—H14B	109.3	C24—C29—H29B	109.4
C9—C14—H14B	109.3	H29A—C29—H29B	108.0
H14A—C14—H14B	108.0	C27—C30—H30A	109.5
C12—C15—H15A	109.5	C27—C30—H30B	109.5
C12—C15—H15B	109.5	H30A—C30—H30B	109.5
H15A—C15—H15B	109.5	C27—C30—H30C	109.5
C12—C15—H15C	109.5	H30A—C30—H30C	109.5
H15A—C15—H15C	109.5	H30B—C30—H30C	109.5
C1—O1—C2—C7	173.31 (10)	C16—O3—C17—C22	177.02 (11)
C1—O1—C2—C3	−7.90 (17)	C16—O3—C17—C18	−3.19 (17)
O1—C2—C3—C4	179.14 (11)	O3—C17—C18—C19	179.81 (11)
C7—C2—C3—C4	−2.13 (17)	C22—C17—C18—C19	−0.41 (18)
C2—C3—C4—C5	1.44 (17)	C17—C18—C19—C20	1.11 (18)
C3—C4—C5—C6	0.71 (17)	C18—C19—C20—C21	−0.56 (18)
C3—C4—C5—C8	−177.36 (10)	C18—C19—C20—C23	177.42 (11)
C4—C5—C6—C7	−2.21 (17)	C19—C20—C21—C22	−0.68 (18)
C8—C5—C6—C7	175.77 (11)	C23—C20—C21—C22	−178.56 (11)
C5—C6—C7—C2	1.54 (17)	C20—C21—C22—C17	1.37 (18)
O1—C2—C7—C6	179.51 (10)	O3—C17—C22—C21	178.99 (11)
C3—C2—C7—C6	0.67 (17)	C18—C17—C22—C21	−0.81 (18)
C4—C5—C8—O2	21.98 (17)	C19—C20—C23—O4	12.43 (18)
C6—C5—C8—O2	−155.99 (12)	C21—C20—C23—O4	−169.69 (12)
C4—C5—C8—C9	−155.03 (11)	C19—C20—C23—C24	−167.66 (11)
C6—C5—C8—C9	27.00 (17)	C21—C20—C23—C24	10.22 (18)
O2—C8—C9—C10	39.30 (16)	O4—C23—C24—C25	−29.70 (16)
C5—C8—C9—C10	−143.71 (11)	C20—C23—C24—C25	150.39 (11)
O2—C8—C9—C14	−82.01 (14)	O4—C23—C24—C29	92.15 (14)
C5—C8—C9—C14	94.98 (13)	C20—C23—C24—C29	−87.76 (13)
C8—C9—C10—C11	−173.66 (11)	C23—C24—C25—C26	177.09 (10)
C14—C9—C10—C11	−54.51 (14)	C29—C24—C25—C26	55.81 (14)
C9—C10—C11—C12	56.90 (15)	C24—C25—C26—C27	−57.41 (14)
C10—C11—C12—C15	179.37 (10)	C25—C26—C27—C30	−179.46 (10)
C10—C11—C12—C13	−56.60 (14)	C25—C26—C27—C28	56.11 (14)
C15—C12—C13—C14	−179.84 (11)	C30—C27—C28—C29	179.88 (11)
C11—C12—C13—C14	56.25 (14)	C26—C27—C28—C29	−55.74 (14)
C12—C13—C14—C9	−55.65 (14)	C27—C28—C29—C24	56.02 (14)
C8—C9—C14—C13	176.27 (10)	C23—C24—C29—C28	−177.67 (10)
C10—C9—C14—C13	53.89 (13)	C25—C24—C29—C28	−54.94 (13)

D—H···A	D—H	H···A	D···A	D—H···A
C9—H9···O2i	1.00	2.57	3.4694 (18)	150
C24—H24···O4ii	1.00	2.60	3.5244 (18)	154

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C9—H9⋯O2i	1.00	2.57	3.4694 (18)	150
C24—H24⋯O4ii	1.00	2.60	3.5244 (18)	154

Symmetry codes: (i) ; (ii) .