Literature DB >> 23111350

Anomalous Staudinger reaction at intramolecular frustrated P-B Lewis pair frameworks.

Annika Stute1, Lukas Heletta, Roland Fröhlich, Constantin G Daniliuc, Gerald Kehr, Gerhard Erker.   

Abstract

The FLP-mesityl azide addition products 5, formed by FLP-addition to the terminal azide nitrogen atom, undergo N-N bond cleavage in an unusual variant of the Staudinger reaction upon thermolysis or photolysis to give an internally borane stabilized [P]=NH phosphinimine and a dimethylindazole derivative.

Entities:  

Year:  2012        PMID： 23111350     DOI： 10.1039/c2cc36782c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Validation of experimental charge-density refinement strategies: when do we overfit?

Authors:  Lennard Krause; Benedikt Niepötter; Christian J Schürmann; Dietmar Stalke; Regine Herbst-Irmer
Journal:  IUCrJ       Date:  2017-05-24       Impact factor: 4.769

2.  Diborane(4) Azides: Surprisingly Stable Sources of Transient Iminoboranes.

Authors:  Torsten Thiess; Guillaume Bélanger-Chabot; Felipe Fantuzzi; Maximilian Michel; Moritz Ernst; Bernd Engels; Holger Braunschweig
Journal:  Angew Chem Int Ed Engl       Date:  2020-05-28       Impact factor: 15.336

3.  Reactions of Mesityl Azide with Ferrocene-Based N-Heterocyclic Germylenes, Stannylenes and Plumbylenes, Including PPh2 -Functionalised Congeners.

Authors:  Robin Guthardt; Lisa Oetzel; Tobias Lang; Clemens Bruhn; Ulrich Siemeling
Journal:  Chemistry       Date:  2022-06-08       Impact factor: 5.020

4.  A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability.

Authors:  Chonghe Zhang; Xiaocui Liu; Junyi Wang; Qing Ye
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-29       Impact factor: 16.823

5.  New Insights in Frustrated Lewis Pair Chemistry with Azides.

Authors:  Devin H A Boom; Andrew R Jupp; Martin Nieger; Andreas W Ehlers; J Chris Slootweg
Journal:  Chemistry       Date:  2019-09-09       Impact factor: 5.236
  5 in total

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