| Literature DB >> 23108283 |
Cristina Pubill-Ulldemolins1, Macarena Poyatos, Carles Bo, Elena Fernández.
Abstract
In rhodium catalysed borylation of cyclic olefins, the synergy between bidentate NHC ligands, that modify cationic Rh(I) species, and the use of non-polar solvents, such as cyclohexane, is the key factor to favour a less energetically demanding route towards the formation of diborated products versus allyl boronate esters.Entities:
Year: 2013 PMID： 23108283 DOI： 10.1039/c2dt31659e
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390