Literature DB >> 23099473

Crystal structure of the ionic liquid EtNH3NO3-insights into the thermal phase behavior of protic ionic liquids.

Wesley A Henderson1, Paul Fylstra, Hugh C De Long, Paul C Trulove, Simon Parsons.   

Abstract

The crystal structure of the salt ethylammonium nitrate (EtNH(3)NO(3)) has been determined. EtNH(3)NO(3) is one of the most widely studied protic ionic liquids (PILs)-ILs formed by proton transfer from a Brønsted acid to a Brønsted base. The structural features from the crystal structure, in concert with a Raman spectroscopic analysis of the ions, provide direct insight as to why EtNH(3)NO(3) melts below ambient temperature, while other related salts (such as EtNH(3)Cl) do not.

Entities:  

Year:  2012        PMID: 23099473     DOI: 10.1039/c2cp43079g

Source DB:  PubMed          Journal:  Phys Chem Chem Phys        ISSN: 1463-9076            Impact factor:   3.676


  1 in total

1.  13C longitudinal relaxation time measurements and DFT-GIAO NMR computations for two ammonium ions of a tetraazamacrocyclic scorpiand system.

Authors:  Ryszard B Nazarski
Journal:  J Incl Phenom Macrocycl Chem       Date:  2013-03-02       Impact factor: 1.633

  1 in total

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