Literature DB >> 23089889

1,5-Migration of rhodium via C-H bond activation in catalytic decyanative silylation of nitriles.

Mamoru Tobisu1, Junya Hasegawa, Yusuke Kita, Hirotaka Kinuta, Naoto Chatani.   

Abstract

Unprecedented aryl-to-aryl 1,5-rhodium migration is involved in decyanative silylation of aryl cyanides bearing a tethered arene. The 1,5-migration proceeds through remote C-H bond activation. 1,5-Migration also occurs in other rhodium-catalyzed reactions, including borylation and oxidative Mizoroki-Heck reactions.

Entities:  

Year:  2012        PMID： 23089889     DOI： 10.1039/c2cc36601k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Fused heteroaromatic dihydrosiloles: synthesis and double-fold modification.

Authors:  Alexey Kuznetsov; Yoshiharu Onishi; Yoshihiro Inamoto; Vladimir Gevorgyan
Journal:  Org Lett       Date:  2013-04-29       Impact factor: 6.005

2.  Catalytic Reductive ortho-C-H Silylation of Phenols with Traceless, Versatile Acetal Directing Groups and Synthetic Applications of Dioxasilines.

Authors:  Yuanda Hua; Parham Asgari; Thirupataiah Avullala; Junha Jeon
Journal:  J Am Chem Soc       Date:  2016-06-16       Impact factor: 15.419
  2 in total

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