| Literature DB >> 23086741 |
Anna Kajetanowicz1, Justyna Czaban, G Rajesh Krishnan, Maura Malińska, Krzysztof Woźniak, Humera Siddique, Ludmila G Peeva, Andrew G Livingston, Karol Grela.
Abstract
New molecular-weight-enlarged metathesis catalysts, which bear polyhedral oligomeric silsesquioxane (POSS) tags, were synthesized and characterized. The catalysts can be recovered from the reaction mixture by using nanofiltration techniques and can be reused. It was found that the membranes Starmem 228 and PuraMem 280 successfully separate the catalyst from the post-reaction mixtures to below 3 ppm. The application of these POSS-tagged catalysts in a continuous metathesis reaction was also investigated.Entities:
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Year: 2012 PMID： 23086741 DOI： 10.1002/cssc.201200466
Source DB: PubMed Journal: ChemSusChem ISSN： 1864-5631 Impact factor: 8.928