Literature DB >> 23083175

Volumes of aqueous hydrogen and hydroxide ions at 0 to 200 °C.

Yizhak Marcus1.   

Abstract

The electrostriction of aqueous hydrogen and hydroxide ions at infinite dilution was calculated by the shell-by-shell method over the temperature range 0 to 200 °C. The calculation required an estimate of the ionic radius of these ions, and comparison with data for aqueous lithium, sodium, and fluoride ions provided values for the nominal sizes of the hydrogen and hydroxide ions in solution. From the volumetric standpoint, these sizes are surprisingly smaller than the size of a water molecule.

Entities:  

Year:  2012        PMID: 23083175     DOI: 10.1063/1.4758071

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  8 in total

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  8 in total

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