Literature DB >> 23065969

The fluoride-free transmetalation of organosilanes to gold.

Stéphanie Dupuy1, Alexandra M Z Slawin, Steven P Nolan.   

Abstract

Golden transfer: The versatile gold(I) complex [Au(IPr)(OH)] permits very straightforward access to a series of aryl-, vinyl- and alkylgold silanolates by reaction with the appropriate silane reagent. These silanolate compounds are key intermediates in a fluoride-free process that results in the net transmetalation of organosilanes to gold.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID： 23065969     DOI： 10.1002/chem.201202299

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  6 in total

1.  Crystal structure of tetrakis-(acetyl-acetonato)di-chloridodi-μ3-methano-lato-tetra-μ2-methano-lato-tetra-iron(III).

Authors:  Casseday P Richers; Jeffery A Bertke; Danielle L Gray; Thomas B Rauchfuss
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-07-29

2.  Synthesis, characterization and luminescence studies of gold(I)-NHC amide complexes.

Authors:  Adrián Gómez-Suárez; David J Nelson; David G Thompson; David B Cordes; Duncan Graham; Alexandra M Z Slawin; Steven P Nolan
Journal:  Beilstein J Org Chem       Date:  2013-10-28       Impact factor: 2.883

3.  Mechanism of the Transmetalation of Organosilanes to Gold.

Authors:  Laura Falivene; David J Nelson; Stéphanie Dupuy; Steven P Nolan; Albert Poater; Luigi Cavallo
Journal:  ChemistryOpen       Date:  2015-09-10       Impact factor: 2.911

4.  Gold-Catalyzed C-H Functionalization with Aryl Germanes.

Authors:  Christoph Fricke; Amit Dahiya; William B Reid; Franziska Schoenebeck
Journal:  ACS Catal       Date:  2019-08-30       Impact factor: 13.084

5.  Gold(I)-Catalyzed Nucleophilic Allylation of Azinium Ions with Allylboronates.

Authors:  Luke O'Brien; Stephen P Argent; Kristaps Ermanis; Hon Wai Lam
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-25       Impact factor: 16.823

6.  Photoinitiated oxidative addition of CF3I to gold(I) and facile aryl-CF3 reductive elimination.

Authors:  Matthew S Winston; William J Wolf; F Dean Toste
Journal:  J Am Chem Soc       Date:  2014-05-16       Impact factor: 15.419
  6 in total

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