| Literature DB >> 23062083 |
Yuehui Li1, Liang-Qiu Lu, Shoubhik Das, Sabine Pisiewicz, Kathrin Junge, Matthias Beller.
Abstract
Unprecedented chemoselective reductions of phosphine oxides to phosphines proceed smoothly in the presence of catalytic amounts of specific Brønsted acids. By utilizing inexpensive silanes, e.g., PMHS or (EtO)(2)MeSiH, other reducible functional groups such as ketones, aldehydes, olefins, nitriles, and esters are well-tolerated under optimized conditions.Entities:
Year: 2012 PMID： 23062083 DOI： 10.1021/ja3069165
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419