Literature DB >> 23042720

Equimolar CO2 capture by N-substituted amino acid salts and subsequent conversion.

An-Hua Liu1, Ran Ma, Chan Song, Zhen-Zhen Yang, Ao Yu, Yu Cai, Liang-Nian He, Ya-Nan Zhao, Bing Yu, Qing-Wen Song.   

Abstract

Steric bulk controls CO(2) absorption: N-substituted amino acid salts in poly(ethylene glycol) reversibly absorb CO(2) in nearly 1:1 stoichiometry. Carbamic acid is thought to be the absorbed form of CO(2); this was supported by NMR and in situ IR spectroscopy, and DFT calculations. The captured CO(2) could be converted directly into oxazolidinones and thus CO(2) desorption could be sidestepped.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID： 23042720     DOI： 10.1002/anie.201205362

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  11 in total

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Review 8.  CO2 Capture and in situ Catalytic Transformation.

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9.  Efficient CO2 capture by tertiary amine-functionalized ionic liquids through Li(+)-stabilized zwitterionic adduct formation.

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10.  CO2 Capture in Ionic Liquids Based on Amino Acid Anions With Protic Side Chains: a Computational Assessment of Kinetically Efficient Reaction Mechanisms.

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