| Literature DB >> 23039713 |
Pei-Qin Liao1, Dong-Dong Zhou, Ai-Xin Zhu, Lu Jiang, Rui-Biao Lin, Jie-Peng Zhang, Xiao-Ming Chen.
Abstract
Using a bis-triazolate ligand and tetrahedral Zn(II) ion, we synthesized a flexible porous coordination polymer functionalized with pairs of uncoordinated triazolate N-donors that can be used as guest chelating sites to give very high CO(2) adsorption enthalpy and CO(2)/N(2) selectivity. The dynamic CO(2) sorption behavior could be monitored well by single-crystal X-ray diffraction.Entities:
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Year: 2012 PMID: 23039713 DOI: 10.1021/ja3073512
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419