Literature DB >> 23038414

Frustrated Lewis pair inspired carbon dioxide reduction by a ruthenium tris(aminophosphine) complex.

Michael J Sgro1, Douglas W Stephan.   

Abstract

Frustrating ruthenium: the ruthenium complex 1 is shown to bind carbon dioxide or aldehyde in a manner similar to a frustrated Lewis pair. Compound 2 catalyzes the reduction of CO(2) in the presence of pinacolborane (HBpin), yielding MeOBpin and O(Bpin)(2) (Ru red, P orange, N green, O light red, C black).
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID: 23038414     DOI: 10.1002/anie.201205741

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  4 in total

1.  Effects of Noncovalent Interactions on High-Spin Fe(IV)-Oxido Complexes.

Authors:  Victoria F Oswald; Justin L Lee; Saborni Biswas; Andrew C Weitz; Kaustuv Mittra; Ruixi Fan; Jikun Li; Jiyong Zhao; Michael Y Hu; Esen E Alp; Emile L Bominaar; Yisong Guo; Michael T Green; Michael P Hendrich; A S Borovik
Journal:  J Am Chem Soc       Date:  2020-06-24       Impact factor: 15.419

2.  Quantifying the efficiency of CO2 capture by Lewis pairs.

Authors:  Jay J Chi; Timothy C Johnstone; Dan Voicu; Paul Mehlmann; Fabian Dielmann; Eugenia Kumacheva; Douglas W Stephan
Journal:  Chem Sci       Date:  2017-02-20       Impact factor: 9.825

3.  Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups.

Authors:  Christina Erken; Akash Kaithal; Suman Sen; Thomas Weyhermüller; Markus Hölscher; Christophe Werlé; Walter Leitner
Journal:  Nat Commun       Date:  2018-10-30       Impact factor: 14.919

4.  CO2 reduction with protons and electrons at a boron-based reaction center.

Authors:  Jordan W Taylor; Alex McSkimming; Laura A Essex; W Hill Harman
Journal:  Chem Sci       Date:  2019-08-06       Impact factor: 9.825

  4 in total

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