Literature DB >> 23019081

Transition-metal-free atropo-selective synthesis of biaryl compounds based on arynes.

Frédéric R Leroux1, Anaïs Berthelot, Laurence Bonnafoux, Armen Panossian, Françoise Colobert.   

Abstract

A modular way towards biaryls: Highly enantioenriched biphenyls can be prepared based on a transition-metal-free aryl-aryl coupling followed by efficient desymmetrization or deracemization and chemoselective functionalization (see scheme).
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID： 23019081     DOI： 10.1002/chem.201202739

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  5 in total

1.  Sustainable and highly controlled aryl couplings revealed by systematic assessment of photoactivatable linkers.

Authors:  Veit G Haensch; Toni Neuwirth; Alexander Bergner; Jakob Bruhnke; Florian Kloss; Christian Hertweck
Journal:  Chem Sci       Date:  2022-04-13       Impact factor: 9.969

2.  Enzymatic desymmetrising redox reactions for the asymmetric synthesis of biaryl atropisomers.

Authors:  Samantha Staniland; Bo Yuan; Nelson Giménez-Agulló; Tommaso Marcelli; Simon C Willies; Damian M Grainger; Nicholas J Turner; Jonathan Clayden
Journal:  Chemistry       Date:  2014-08-22       Impact factor: 5.236

3.  SET-induced biaryl cross-coupling: an S(RN)1 reaction.

Authors:  Brandon E Haines; Olaf Wiest
Journal:  J Org Chem       Date:  2014-03-06       Impact factor: 4.354

4.  BN-Substitution in Dithienylpyrenes Prevents Excimer Formation in Solution and in the Solid State.

Authors:  Yannik Appiarius; Philipp J Gliese; Stephan A W Segler; Pascal Rusch; Jiangbin Zhang; Paul J Gates; Rumpa Pal; Lorraine A Malaspina; Kunihisa Sugimoto; Tim Neudecker; Nadja C Bigall; Simon Grabowsky; Artem A Bakulin; Anne Staubitz
Journal:  J Phys Chem C Nanomater Interfaces       Date:  2022-02-24       Impact factor: 4.126

5.  Metal Free Bi(hetero)aryl Synthesis: A Benzyne Truce-Smiles Rearrangement.

Authors:  Catherine M Holden; Shariar M A Sohel; Michael F Greaney
Journal:  Angew Chem Int Ed Engl       Date:  2016-01-13       Impact factor: 15.336
  5 in total

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