Literature DB >> 23005764

Mode-coupling theory of the glass transition for confined fluids.

Simon Lang1, Rolf Schilling, Vincent Krakoviack, Thomas Franosch.   

Abstract

We present a detailed derivation of a microscopic theory for the glass transition of a liquid enclosed between two parallel walls relying on a mode-coupling approximation. This geometry lacks translational invariance perpendicular to the walls, which implies that the density profile and the density-density correlation function depends explicitly on the distances to the walls. We discuss the residual symmetry properties in slab geometry and introduce a symmetry adapted complete set of two-point correlation functions. Since the currents naturally split into components parallel and perpendicular to the walls the mathematical structure of the theory differs from the established mode-coupling equations in bulk. We prove that the equations for the nonergodicity parameters still display a covariance property similar to bulk liquids.

Year:  2012        PMID: 23005764     DOI: 10.1103/PhysRevE.86.021502

Source DB:  PubMed          Journal:  Phys Rev E Stat Nonlin Soft Matter Phys        ISSN: 1539-3755


  2 in total

1.  Simulated glass-forming polymer melts: dynamic scattering functions, chain length effects, and mode-coupling theory analysis.

Authors:  S Frey; F Weysser; H Meyer; J Farago; M Fuchs; J Baschnagel
Journal:  Eur Phys J E Soft Matter       Date:  2015-02-26       Impact factor: 1.890

2.  Layering and packing in confined colloidal suspensions.

Authors:  Alejandro Villada-Balbuena; Gerhard Jung; Angel B Zuccolotto-Bernez; Thomas Franosch; Stefan U Egelhaaf
Journal:  Soft Matter       Date:  2022-06-29       Impact factor: 4.046

  2 in total

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