Literature DB >> 22998336

Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzooxasilines via enantioselective transmetalation.

Ryo Shintani1, Eleanor E Maciver, Fumiko Tamakuni, Tamio Hayashi.   

Abstract

A rhodium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzooxasilines has been developed. High enantioselectivities have been achieved by employing (S,S)-Me-Duphos as the ligand through "enantioselective transmetalation".

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Year:  2012        PMID： 22998336     DOI： 10.1021/ja3076555

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds.

Authors:  Bo Su; Tai-Gang Zhou; Xian-Wei Li; Xiao-Ru Shao; Pei-Lin Xu; Wen-Lian Wu; John F Hartwig; Zhang-Jie Shi
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-15       Impact factor: 15.336

2.  Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic silicon-bridged arylpyridinones.

Authors:  Ryo Shintani; Ryo Takano; Kyoko Nozaki
Journal:  Chem Sci       Date:  2015-11-09       Impact factor: 9.825

3.  Organocatalytic Asymmetric Synthesis of Si-Stereogenic Silyl Ethers.

Authors:  Hui Zhou; Jung Tae Han; Nils Nöthling; Monika M Lindner; Judith Jenniches; Clemens Kühn; Nobuya Tsuji; Li Zhang; Benjamin List
Journal:  J Am Chem Soc       Date:  2022-06-01       Impact factor: 16.383

4.  Enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles.

Authors:  Shuyou Chen; Delong Mu; Pei-Lin Mai; Jie Ke; Yingzi Li; Chuan He
Journal:  Nat Commun       Date:  2021-02-23       Impact factor: 14.919
  4 in total

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