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Literature DB >> 22997099

A thermally stable gold(III) hydride: synthesis, reactivity, and reductive condensation as a route to gold(II) complexes.

Dragoş-Adrian Roşca¹, Dan A Smith, David L Hughes, Manfred Bochmann.

Abstract

Going for gold: The first thermally stable gold(III) hydride [(C N C)*AuH] is presented. It undergoes regioselective insertions with allenes to give gold(III) vinyl complexes, and reductive condensation with [(C N C)*AuOH] to the air-stable Au(II) product, [(C N C)*(2)Au(2)], with a short nonbridged gold-gold bond.

Entities: Chemical Gene

Year: 2012 PMID： 22997099 DOI： 10.1002/anie.201206468

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

15 in total

1. Evidence for genuine hydrogen bonding in gold(I) complexes.

Authors: Mathilde Rigoulet; Stéphane Massou; E Daiann Sosa Carrizo; Sonia Mallet-Ladeira; Abderrahmane Amgoune; Karinne Miqueu; Didier Bourissou
Journal: Proc Natl Acad Sci U S A Date: 2018-12-19 Impact factor: 11.205

2. Dinuclear Au(I), Au(II) and Au(III) Complexes with (CF₂ )_n Chains: Insights into The Role of Aurophilic Interactions in the Au(I) Oxidation.

Authors: Alejandro Portugués; Delia Bautista; Juan Gil-Rubio
Journal: Chemistry Date: 2021-09-29 Impact factor: 5.020

3. Reactivity of the [Au(C^N^C)Cl] complex in the presence of H₂O and N-, S- and Se-containing nucleophiles: a DFT study.

Authors: G Y Sánchez Delgado; D Paschoal; H F Dos Santos
Journal: J Biol Inorg Chem Date: 2018-09-12 Impact factor: 3.358

A thermally stable gold(III) hydride: synthesis, reactivity, and reductive condensation as a route to gold(II) complexes.

1. Evidence for genuine hydrogen bonding in gold(I) complexes.

2. Dinuclear Au(I), Au(II) and Au(III) Complexes with (CF₂ )_n Chains: Insights into The Role of Aurophilic Interactions in the Au(I) Oxidation.

3. Reactivity of the [Au(C^N^C)Cl] complex in the presence of H₂O and N-, S- and Se-containing nucleophiles: a DFT study.

4. Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors.

5. Stable gold(III) catalysts by oxidative addition of a carbon-carbon bond.

6. Synthesis and luminescence modulation of pyrazine-based gold(III) pincer complexes.

7. Stereo- and Regioselective Alkyne Hydrometallation with Gold(III) Hydrides.

8. Formation of Gold(III) Alkyls from Gold Alkoxide Complexes.

9. An element through the looking glass: exploring the Au-C, Au-H and Au-O energy landscape.

10. Gold(III)-CO and gold(III)-CO2 complexes and their role in the water-gas shift reaction.