Literature DB >> 22992207

Oxidative cleavage of α-aryl aldehydes using iodosylbenzene.

Nizam Havare1, Dietmar A Plattner.   

Abstract

We found that α-aryl aldehydes can be cleaved to chain-shortened carbonyl compounds and formaldehyde by various iodosylbenzene complexes. A mechanistic scheme is presented that accounts for the loss of one carbon atom. Formaldehyde is further oxidized to CO and CO(2) under the reaction conditions.

Entities:  

Year:  2012        PMID： 22992207     DOI： 10.1021/ol301675v

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  The Two Faces of Tetramethylcyclam in Iron Chemistry: Distinct Fe-O-M Complexes Derived from [FeIV(Oanti/syn)(TMC)]2+ Isomers.

Authors:  Ang Zhou; Jai Prakash; Gregory T Rohde; Johannes E M N Klein; Scott T Kleespies; Apparao Draksharapu; Ruixi Fan; Yisong Guo; Christopher J Cramer; Lawrence Que
Journal:  Inorg Chem       Date:  2016-12-21       Impact factor: 5.165

2.  Oxoiron(IV) complexes as synthons for the assembly of heterobimetallic centers such as the Fe/Mn active site of Class Ic ribonucleotide reductases.

Authors:  Ang Zhou; Patrick M Crossland; Apparao Draksharapu; Andrew J Jasniewski; Scott T Kleespies; Lawrence Que
Journal:  J Biol Inorg Chem       Date:  2017-12-07       Impact factor: 3.358

Review 3.  Glycosylation reactions mediated by hypervalent iodine: application to the synthesis of nucleosides and carbohydrates.

Authors:  Yuichi Yoshimura; Hideaki Wakamatsu; Yoshihiro Natori; Yukako Saito; Noriaki Minakawa
Journal:  Beilstein J Org Chem       Date:  2018-06-28       Impact factor: 2.883

4.  Characterization of the Fleeting Hydroxoiron(III) Complex of the Pentadentate TMC-py Ligand.

Authors:  Wei-Min Ching; Ang Zhou; Johannes E M N Klein; Ruixi Fan; Gerald Knizia; Christopher J Cramer; Yisong Guo; Lawrence Que
Journal:  Inorg Chem       Date:  2017-08-31       Impact factor: 5.165
  4 in total

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