Literature DB >> 22987543

[{Fe(CO)3}4{SnI}6I4]2-: the first bimetallic adamantane-like cluster.

Silke Wolf1, Florian Winter, Rainer Pöttgen, Nils Middendorf, Wim Klopper, Claus Feldmann.   

Abstract

Show some metal: the first bimetallic adamantane-like cluster, [{Fe(CO)(3)}(4){SnI}(6)I(4)](2-), was prepared by an ionic-liquid-based synthesis. The valence states of iron and tin were verified based on bond-length considerations, FT-IR and (119)Sn Mössbauer spectroscopy, as well as with DFT calculations.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID: 22987543     DOI: 10.1002/chem.201202683

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  2 in total

Review 1.  Controlled Synthesis of Polyions of Heavy Main-Group Elements in Ionic Liquids.

Authors:  Matthias F Groh; Alexander Wolff; Matthias A Grasser; Michael Ruck
Journal:  Int J Mol Sci       Date:  2016-09-01       Impact factor: 5.923

2.  Ge-Fe Carbonyl Cluster Compounds: Ionic Liquids-Based Synthesis, Structures, and Properties.

Authors:  Silke Wolf; Alexander Egeberg; Jens Treptow; Claus Feldmann
Journal:  ChemistryOpen       Date:  2020-11-23       Impact factor: 2.630

  2 in total

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