Literature DB >> 22976927

Quantitative emergence of hetero[4]rotaxanes by template-directed click chemistry.

Chenfeng Ke1, Ronald A Smaldone, Takashi Kikuchi, Hao Li, Anthony P Davis, J Fraser Stoddart.   

Abstract

In one fell swoop, polyrotaxanes comprising up to 64 rings can be synthesized as a result of cucurbit[6]uril-templated 1,3-dipolar azide-alkyne cycloadditions accelerated in the presence of cyclodextrins as a consequence of self-sorting and positive cooperativity, brought about by hydrogen bonding. Mixing six components in one pot affords a hetero[4]rotaxane in one minute in quantitative yield.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID: 22976927     DOI: 10.1002/anie.201205087

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  14 in total

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3.  One-pot synthesis of hetero[6]rotaxane bearing three different kinds of macrocycle through a self-sorting process.

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4.  One-pot synthesis of a [c2]daisy-chain-containing hetero[4]rotaxane via a self-sorting strategy.

Authors:  Xin Fu; Qi Zhang; Si-Jia Rao; Da-Hui Qu; He Tian
Journal:  Chem Sci       Date:  2016-01-12       Impact factor: 9.825

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6.  Efficient catenane synthesis by cucurbit[6]uril-mediated azide-alkyne cycloaddition.

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Review 10.  Probing Reversible Guest Binding with Hyperpolarized 129Xe-NMR: Characteristics and Applications for Cucurbit[n]urils.

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