Distribution pattern of polycyclic aromatic hydrocarbons in particle-size fractions of coking plant soils from different depth.

The concentrations of 16 priority polycyclic aromatic hydrocarbons (PAHs) in four size fractions (<2, 2-20, 20-200, >200 μm) in soils at different depth from a heavily contaminated crude benzol production facility of a coking plant were determined using GC-MS. Vertically, elevated total PAHs concentrations were observed in the soils at 3.0-4.5 m (layer B) and 6.0-7.5 m (layer C), relatively lower at 1.5-3.0 m (layer A) and 10.5-12.0 m (layer D). At all sampling sites, the silt (2-20 μm) contained the highest PAHs concentration (ranged from 726 to 2,711 mg/kg). Despite the substantial change in PAHs concentrations in soils with different particle sizes and lithologies, PAHs composition was similarly dominated by 2-3 ring species (86.5-98.3 %), including acenaphthene, fluorene, and phenanthrene. For the contribution of PAHs mass in each fraction to the bulk soil, the 20-200 μm size fraction had the greatest accumulation of PAHs in loamy sand layers at 1.0-7.5 m, increasing with depth; while in deeper sand layer at 10.5-12.0 m, the >200 μm size fraction showed highest percentages and contributed 81 % of total PAHs mass. For individual PAH distribution, the 2-3 ring PAHs were highly concentrated in the small size fraction (<2 and 2-20 μm); the 4-6 ring PAHs showed the highest concentrations in the 2-20 μm size fraction, increasing with depth. The distribution of PAHs was primarily determined by the sorption on soil organic matter and the characteristics of PAHs. This research should have significant contribution to PAH migration study and remediation design for PAHs-contaminated sites.