Literature DB >> 22968902

Dinuclear palladium complexes--precursors or catalysts?

Robert S Paton1, John M Brown.   

Abstract

Calculations help: Recent work from Schoenebeck's group has demonstrated beyond reasonable doubt that the dimeric LPd(I) Br catalysts that are widely used in coupling chemistry operate through prior formal reduction to an LPd(0) species. Conversely, L(2)Pd(0) catalysts can be activated by oxidation. In other cases a binuclear species can persist through the catalytic cycle.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 22968902     DOI： 10.1002/anie.201205417

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  6 in total

1.  A Dinuclear Mechanism Implicated in Controlled Carbene Polymerization.

Authors:  Aleksandr V Zhukhovitskiy; Ilia J Kobylianskii; Andy A Thomas; Austin M Evans; Connor P Delaney; Nathan C Flanders; Scott E Denmark; William R Dichtel; F Dean Toste
Journal:  J Am Chem Soc       Date:  2019-04-09       Impact factor: 15.419

2.  Dipalladium(I) terphenyl diphosphine complexes as models for two-site adsorption and activation of organic molecules.

Authors:  Sibo Lin; David E Herbert; Alexandra Velian; Michael W Day; Theodor Agapie
Journal:  J Am Chem Soc       Date:  2013-10-10       Impact factor: 15.419

3.  C2-Symmetric Dinickel Catalysts for Enantioselective [4 + 1]-Cycloadditions.

Authors:  Michael J Behlen; Christopher Uyeda
Journal:  J Am Chem Soc       Date:  2020-09-30       Impact factor: 15.419

Review 4.  Dinuclear Nickel(I) and Palladium(I) Complexes for Highly Active Transformations of Organic Compounds.

Authors:  Takahiro Inatomi; Yuji Koga; Kouki Matsubara
Journal:  Molecules       Date:  2018-01-11       Impact factor: 4.411

5.  Modular Functionalization of Arenes in a Triply Selective Sequence: Rapid C(sp2 ) and C(sp3 ) Coupling of C-Br, C-OTf, and C-Cl Bonds Enabled by a Single Palladium(I) Dimer.

Authors:  Sinead T Keaveney; Gourab Kundu; Franziska Schoenebeck
Journal:  Angew Chem Int Ed Engl       Date:  2018-08-27       Impact factor: 15.336

6.  A Next-Generation Air-Stable Palladium(I) Dimer Enables Olefin Migration and Selective C-C Coupling in Air.

Authors:  Gourab Kundu; Theresa Sperger; Kari Rissanen; Franziska Schoenebeck
Journal:  Angew Chem Int Ed Engl       Date:  2020-09-28       Impact factor: 15.336
  6 in total

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