Determination of gold in geological materials by carbon slurry sampling graphite furnace atomic absorption spectrometry.

A simple and cost effective preconcentration method on modified activated carbons is described for the determination of traces of gold (Au) in geological samples by carbon slurry sampling graphite furnace atomic absorption spectrometry (GFAAS). The basic parameters affecting the adsorption capacity of Au(III) ions on modified activated carbons were studied in detail and the effect of activated carbons modification has been determined by studying the initial runs of adsorption isotherms. The influence of chlorides and nitrates on adsorption ability of Au(III) ions onto the modified activated carbons for diluted aqueous solution was also studied in detail in respect to the determination of gold in solid materials after digestion steps in the analytical procedure, which usually involves the application of aqua regia. SEM-EDX and XPS studies confirmed that the surface reduction of Au(III) ions to Au(0) is the main gold adsorption mechanism on the activated carbon. Determination of gold after its preconcentration on the modified activated carbon was validated by applying certified reference materials. The experimental results are in good agreement with the certified values. The proposed method has been successfully applied for the determination of Au in real samples using aqueous standards.