Literature DB >> 22965553

A functional-group-tolerant catalytic trans hydrogenation of alkynes.

Karin Radkowski1, Basker Sundararaju, Alois Fürstner.   

Abstract

Against the rules: during the hundred years following Sabatier's groundbreaking work on catalytic hydrogenation, syn delivery of the H atoms to the π system of a substrate remained the governing stereochemical rule. An exception has now be found with the use of cationic [Cp*Ru] templates, which accounts for the first practical, functional-group-tolerant, broadly applicable and highly E-selective semihydrogenation method for alkynes.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 22965553     DOI： 10.1002/anie.201205946

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  26 in total

1.  A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes.

Authors:  Konstantin Chernichenko; Adám Madarász; Imre Pápai; Martin Nieger; Markku Leskelä; Timo Repo
Journal:  Nat Chem       Date:  2013-07-07       Impact factor: 24.427

2.  Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal-Ligand Cooperation.

Authors:  Yaoyu Liang; Uttam Kumar Das; Jie Luo; Yael Diskin-Posner; Liat Avram; David Milstein
Journal:  J Am Chem Soc       Date:  2022-10-04       Impact factor: 16.383

3.  Enantioselective Synthesis of Trisubstituted Allenyl-B(pin) Compounds by Phosphine-Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Integrity of Cu-Allenyl Intermediates.

Authors:  Youming Huang; Juan Del Pozo; Sebastian Torker; Amir H Hoveyda
Journal:  J Am Chem Soc       Date:  2018-02-08       Impact factor: 15.419

4.  Light-Driven gem Hydrogenation: An Orthogonal Entry into "Second-Generation" Ruthenium Carbene Catalysts for Olefin Metathesis.

Authors:  Raphael J Zachmann; Alois Fürstner
Journal:  Chemistry       Date:  2021-05-01       Impact factor: 5.236

5.  trans-Hydrogenation: application to a concise and scalable synthesis of brefeldin A.

Authors:  Michael Fuchs; Alois Fürstner
Journal:  Angew Chem Int Ed Engl       Date:  2015-02-04       Impact factor: 15.336

6.  Formation of Ruthenium Carbenes by gem-Hydrogen Transfer to Internal Alkynes: Implications for Alkyne trans-Hydrogenation.

Authors:  Markus Leutzsch; Larry M Wolf; Puneet Gupta; Michael Fuchs; Walter Thiel; Christophe Farès; Alois Fürstner
Journal:  Angew Chem Weinheim Bergstr Ger       Date:  2015-08-31

Review 7.  Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion.

Authors:  Alois Fürstner
Journal:  ACS Cent Sci       Date:  2016-10-27       Impact factor: 14.553

8.  trans-Hydrogenation: Application to a Concise and Scalable Synthesis of Brefeldin A.

Authors:  Michael Fuchs; Alois Fürstner
Journal:  Angew Chem Weinheim Bergstr Ger       Date:  2015-02-04

9.  Kinetically E-selective macrocyclic ring-closing metathesis.

Authors:  Xiao Shen; Thach T Nguyen; Ming Joo Koh; Dongmin Xu; Alexander W H Speed; Richard R Schrock; Amir H Hoveyda
Journal:  Nature       Date:  2017-01-09       Impact factor: 49.962

10.  Formation of ruthenium carbenes by gem-hydrogen transfer to internal alkynes: implications for alkyne trans-hydrogenation.

Authors:  Markus Leutzsch; Larry M Wolf; Puneet Gupta; Michael Fuchs; Walter Thiel; Christophe Farès; Alois Fürstner
Journal:  Angew Chem Int Ed Engl       Date:  2015-08-31       Impact factor: 15.336
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