| Literature DB >> 22954306 |
Iou-Sheng Ke1, Mykhaylo Myahkostupov, Felix N Castellano, François P Gabbaï.
Abstract
The 9-anthryltriphenylstibonium cation, [1](+), has been synthesized and used as a sensor for the toxic fluoride anion in water. This stibonium cation complexes fluoride ions to afford the corresponding fluorostiborane 1-F. This reaction, which occurs at fluoride concentrations in the parts per million range, is accompanied by a drastic fluorescence turn-on response. It is also highly selective and can be used in plain tap water or bottled water to test fluoridation levels.Entities:
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Year: 2012 PMID： 22954306 DOI： 10.1021/ja308194w
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419