| Literature DB >> 22946499 |
Chen Fu1, Marianne Wenzel, Elisabeth Treutlein, Klaus Harms, Eric Meggers.
Abstract
A straightforward method for the synthesis of virtually enantiomerically pure ruthenium(II) polypyridyl complexes [Ru(pp)(pp')(pp")](PF(6))(2), pp = bidentate polypyridyl has been developed. The synthesis draws from the readily available racemic starting material cis-[Ru(pp)(pp')Cl(2)] and the natural amino acids l- or d-proline and relies on a dynamic asymmetric transformation under thermodynamic control.Entities:
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Year: 2012 PMID： 22946499 DOI： 10.1021/ic3015157
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165