Literature DB >> 22938244

Microscopic models of mode-coupling theory: the F12 scenario.

Jeferson J Arenzon1, Mauro Sellitto.   

Abstract

We provide extended evidence that mode-coupling theory (MCT) of supercooled liquids for the F(12) schematic model admits a microscopic realization based on facilitated spin models with tunable facilitation. Depending on the facilitation strength, one observes two distinct dynamical glass transition lines--continuous and discontinuous--merging at a dynamical tricritical-like point with critical decay exponents consistently related by MCT predictions. The mechanisms of dynamical arrest can be naturally interpreted in geometrical terms: the discontinuous and continuous transitions correspond to bootstrap and standard percolation processes, in which the incipient spanning cluster of frozen spins forms either a compact or a fractal structure, respectively. Our cooperative dynamical facilitation picture of glassy behavior is complementary to the one based on disordered systems and can account for higher-order singularity scenarios in the absence of a finite temperature thermodynamic glass transition. We briefly comment on the relevance of our results to finite spatial dimensions and to the F(13) schematic model.

Entities:  

Year:  2012        PMID: 22938244     DOI: 10.1063/1.4746695

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  2 in total

Review 1.  The Interplay between the Theories of Mode Coupling and of Percolation Transition in Attractive Colloidal Systems.

Authors:  Francesco Mallamace; Giuseppe Mensitieri; Martina Salzano de Luna; Paola Lanzafame; Georgia Papanikolaou; Domenico Mallamace
Journal:  Int J Mol Sci       Date:  2022-05-10       Impact factor: 6.208

2.  Scaling and universality in glass transition.

Authors:  Antonio de Candia; Annalisa Fierro; Antonio Coniglio
Journal:  Sci Rep       Date:  2016-05-25       Impact factor: 4.379

  2 in total

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