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Literature DB >> 22936630

Symmetry breaking in the self-assembly of partially fluorinated benzene-1,3,5-tricarboxamides.

Patrick J M Stals¹, Peter A Korevaar, Martijn A J Gillissen, Tom F A de Greef, Carel F C Fitié, Rint P Sijbesma, Anja R A Palmans, E W Meijer.

Abstract

The interplay of two subsequent aggregation processes results in a symmetry-breaking phenomenon in an achiral self-assembling system. Partially fluorinated benzene-1,3,5-tricarboxamide molecules self-assemble into a racemic mixture of one-dimensional P- and M-helical aggregates, followed by bundling into optically active higher-order aggregates or fibers.

Entities: Chemical

Year: 2012 PMID： 22936630 DOI： 10.1002/anie.201204727

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

9 in total

1. Living supramolecular polymerization realized through a biomimetic approach.

Authors: Soichiro Ogi; Kazunori Sugiyasu; Swarup Manna; Sadaki Samitsu; Masayuki Takeuchi
Journal: Nat Chem Date: 2014-02-02 Impact factor: 24.427

2. Unusual analyte-matrix adduct ions and mechanism of their formation in MALDI TOF MS of benzene-1,3,5-tricarboxamide and urea compounds.

Authors: Xianwen Lou; Michel Fransen; Patrick J M Stals; Tristan Mes; Ralf Bovee; Joost J L van Dongen; E W Meijer
Journal: J Am Soc Mass Spectrom Date: 2013-06-29 Impact factor: 3.109

Review 3. Switching between Phosphorescence and Fluorescence Controlled by Chiral Self-Assembly.

Authors: Guofeng Liu; Yanli Zhao
Journal: Adv Sci (Weinh) Date: 2017-05-15 Impact factor: 16.806

4. Solvent Assisted Tuning of Morphology of a Peptide-Perylenediimide Conjugate: Helical Fibers to Nano-Rings and their Differential Semiconductivity.

Authors: Sahnawaz Ahmed; Bapan Pramanik; K N Amba Sankar; Abhinav Srivastava; Nilotpal Singha; Payel Dowari; Arpita Srivastava; Kallol Mohanta; Ananya Debnath; Debapratim Das
Journal: Sci Rep Date: 2017-08-25 Impact factor: 4.379

Symmetry breaking in the self-assembly of partially fluorinated benzene-1,3,5-tricarboxamides.

1. Living supramolecular polymerization realized through a biomimetic approach.

2. Unusual analyte-matrix adduct ions and mechanism of their formation in MALDI TOF MS of benzene-1,3,5-tricarboxamide and urea compounds.

Review 3. Switching between Phosphorescence and Fluorescence Controlled by Chiral Self-Assembly.

4. Solvent Assisted Tuning of Morphology of a Peptide-Perylenediimide Conjugate: Helical Fibers to Nano-Rings and their Differential Semiconductivity.

5. Unravelling the Pathway Complexity in Conformationally Flexible N-Centered Triarylamine Trisamides.

6. Dynamic propeller conformation for the unprecedentedly high degree of chiral amplification of supramolecular helices.

7. Unexpected right-handed helical nanostructures co-assembled from l-phenylalanine derivatives and achiral bipyridines.

Review 8. Revising Complex Supramolecular Polymerization under Kinetic and Thermodynamic Control.

9. Control over the emerging chirality in supramolecular gels and solutions by chiral microvortices in milliseconds.