| Literature DB >> 22935655 |
Claire Lydon1, Mercè Martin Sabi, Mark D Symes, De-Liang Long, Mark Murrie, Shunsuke Yoshii, Hiroyuki Nojiri, Leroy Cronin.
Abstract
Herein we report two structurally intriguing Co(ii)-substituted polyoxometalates, a {Co(9)[P(2)W(15)](3)} and {Co(14)[P(2)W(15)](4)} (compounds 1 and 2) that are formed from the same building blocks under subtly different conditions. Compound 1 displays a structure previously predicted but never before realised, whilst compound 2 is the first Co-containing Dawson-based single-molecule magnet and has a unique cruciform structure.Entities:
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Year: 2012 PMID： 22935655 DOI： 10.1039/c2cc34865a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222