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Literature DB >> 22933046

An N-heterocyclic carbene adduct of diatomic tin, :Sn=Sn:.

Cameron Jones¹, Anastas Sidiropoulos, Nicole Holzmann, Gernot Frenking, Andreas Stasch.

Abstract

Reduction of an N-heterocyclic carbene (NHC) adduct of SnCl(2), viz. [(IPr)SnCl(2)] (IPr = :C{N(Dip)C(H)}(2); Dip = 2,6-diisopropylphenyl), with a magnesium(I) dimer, has afforded the first NHC complex of a row 5 element in its diatomic form, [(IPr)Sn=Sn(IPr)]; a computational analysis of the complex indicates that it comprises a singlet state, doubly bonded tin(0) fragment, :Sn=Sn:, datively bonded by two NHC ligands.

Entities: Chemical Disease Gene

Year: 2012 PMID： 22933046 DOI： 10.1039/c2cc35228a

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

10 in total

1. Generation of 1,2-azaboretidines via reduction of ADC borane adducts.

Authors: H Braunschweig; A Gackstatter; T Kupfer; T Scheller; F Hupp; A Damme; N Arnold; W C Ewing
Journal: Chem Sci Date: 2015-04-16 Impact factor: 9.825

2. Carbene-Stabilized Main Group Radicals and Radical Ions.

Authors: Caleb D Martin; Michele Soleilhavoup; Guy Bertrand
Journal: Chem Sci Date: 2013-08-01 Impact factor: 9.825

3. Neutral zero-valent s-block complexes with strong multiple bonding.

Authors: Merle Arrowsmith; Holger Braunschweig; Mehmet Ali Celik; Theresa Dellermann; Rian D Dewhurst; William C Ewing; Kai Hammond; Thomas Kramer; Ivo Krummenacher; Jan Mies; Krzysztof Radacki; Julia K Schuster
Journal: Nat Chem Date: 2016-06-06 Impact factor: 24.427

4. N-heterocyclic carbene induced reductive coupling of phosphorus tribromide. Isolation of a bromine bridged P-P bond and its subsequent reactivity.

Authors: Jordan B Waters; Thomas A Everitt; William K Myers; Jose M Goicoechea
Journal: Chem Sci Date: 2016-07-20 Impact factor: 9.825

5. Rational synthesis of normal, abnormal and anionic NHC-gallium alkyl complexes: structural, stability and isomerization insights.

Authors: Marina Uzelac; Alberto Hernán-Gómez; David R Armstrong; Alan R Kennedy; Eva Hevia
Journal: Chem Sci Date: 2015-07-03 Impact factor: 9.825

An N-heterocyclic carbene adduct of diatomic tin, :Sn=Sn:.

1. Generation of 1,2-azaboretidines via reduction of ADC borane adducts.

2. Carbene-Stabilized Main Group Radicals and Radical Ions.

3. Neutral zero-valent s-block complexes with strong multiple bonding.

4. N-heterocyclic carbene induced reductive coupling of phosphorus tribromide. Isolation of a bromine bridged P-P bond and its subsequent reactivity.

5. Rational synthesis of normal, abnormal and anionic NHC-gallium alkyl complexes: structural, stability and isomerization insights.

6. Phosphine and carbene azido-cations: [(L)N₃]⁺ and [(L)₂N₃]^.

7. Isolation of Carbene-Stabilized Arsenic Monophosphide [AsP] and its Radical Cation [AsP]^+. and Dication [AsP]².

8. Bonding and stability of donor ligand-supported heavier analogues of cyanogen halides (L')PSi(X)(L).

9. The Heaviest Bottleable Metallylone: Synthesis of a Monatomic, Zero-Valent Lead Complex ("Plumbylone").

10. Distannabarrelenes with Three Coordinated Sn^II Atoms.