Literature DB >> 22932821

Copper-catalyzed cyanation of arenes using benzyl nitrile as a cyanide anion surrogate.

Jisong Jin1, Qiaodong Wen, Ping Lu, Yanguang Wang.   

Abstract

The copper-catalyzed cyanation of arenes using benzyl nitrile as a cyanide anion surrogate furnishes aromatic nitriles in moderate to good yields. The cascade process involves a copper-catalyzed aerobic C-H oxidation, a retro-cyanohydrination, and a copper-catalyzed aerobic oxidative C-H functionalization.

Entities:  

Year:  2012        PMID： 22932821     DOI： 10.1039/c2cc35046g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

Review 1.  Aerobic copper-catalyzed organic reactions.

Authors:  Scott E Allen; Ryan R Walvoord; Rosaura Padilla-Salinas; Marisa C Kozlowski
Journal:  Chem Rev       Date:  2013-06-20       Impact factor: 60.622

2.  One-pot regioselective C-H activation iodination-cyanation of 2,4-diarylquinazolines using malononitrile as a cyano source.

Authors:  Ziqiao Yan; Banlai Ouyang; Xunchun Mao; Wei Gao; Zhihong Deng; Yiyuan Peng
Journal:  RSC Adv       Date:  2019-06-11       Impact factor: 4.036

3.  Copper-catalyzed aerobic radical C-C bond cleavage of N-H ketimines.

Authors:  Ya Lin Tnay; Gim Yean Ang; Shunsuke Chiba
Journal:  Beilstein J Org Chem       Date:  2015-10-19       Impact factor: 2.883
  3 in total

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