| Literature DB >> 22931361 |
Qisheng Zhang1, Jie Li, Katsuyuki Shizu, Shuping Huang, Shuzo Hirata, Hiroshi Miyazaki, Chihaya Adachi.
Abstract
Efficient thermally activated delayed fluorescence (TADF) has been characterized for a carbazole/sulfone derivative in both solutions and doped films. A pure blue organic light emitting diode (OLED) based on this compound demonstrates a very high external quantum efficiency (EQE) of nearly 10% at low current density. Because TADF only occurs in a bipolar system where donor and acceptor centered (3)ππ* states are close to or higher than the triplet intramolecular charge transfer ((3)CT) state, control of the π-conjugation length of both donor and acceptor is considered to be as important as breaking the π-conjugation between them in blue TADF material design.Entities:
Year: 2012 PMID: 22931361 DOI: 10.1021/ja306538w
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419