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Literature DB >> 22931196

Activation of hydrogen and hydrogenation catalysis by a borenium cation.

Jeffrey M Farrell¹, Jillian A Hatnean, Douglas W Stephan.

Abstract

The readily prepared borenium salt [(IiPr(2))(BC(8)H(14))][B(C(6)F(5))(4)] (2) [IiPr(2) = C(3)H(2)(NiPr)(2)] is shown to activate H(2) heterolytically in the presence of tBu(3)P. Compound 2 also acts as a catalyst for the metal-free hydrogenation of imines and enamines at room temperature.

Entities: Chemical

Year: 2012 PMID： 22931196 DOI： 10.1021/ja307995f

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

17 in total

1. A Cationic NHC-Supported Borole.

Authors: Tobias Heitkemper; Christian P Sindlinger
Journal: Chemistry Date: 2020-08-13 Impact factor: 5.236

2. Thermal Dehydrogenation of Base-Stabilized B2H5(+) Complexes and Its Role in C-H Borylation.

Authors: Aleksandrs Prokofjevs
Journal: Angew Chem Int Ed Engl Date: 2015-09-17 Impact factor: 15.336

3. Lewis Base Activation of Lewis Acids - Group 13. In Situ Generation and Reaction of Borenium Ions.

Authors: Scott E Denmark; Yusuke Ueki
Journal: Organometallics Date: 2013-11-25 Impact factor: 3.876

4. Weakly stabilized primary borenium cations and their dicationic dimers.

Authors: Aleksandrs Prokofjevs; Jeff W Kampf; Andrey Solovyev; Dennis P Curran; Edwin Vedejs
Journal: J Am Chem Soc Date: 2013-10-10 Impact factor: 15.419

5. A combined "electrochemical-frustrated lewis pair" approach to hydrogen activation: surface catalytic effects at platinum electrodes.

Authors: Elliot J Lawrence; Robin J Blagg; David L Hughes; Andrew E Ashley; Gregory G Wildgoose
Journal: Chemistry Date: 2014-11-07 Impact factor: 5.236

Activation of hydrogen and hydrogenation catalysis by a borenium cation.

1. A Cationic NHC-Supported Borole.

2. Thermal Dehydrogenation of Base-Stabilized B2H5(+) Complexes and Its Role in C-H Borylation.

3. Lewis Base Activation of Lewis Acids - Group 13. In Situ Generation and Reaction of Borenium Ions.

4. Weakly stabilized primary borenium cations and their dicationic dimers.

5. A combined "electrochemical-frustrated lewis pair" approach to hydrogen activation: surface catalytic effects at platinum electrodes.

6. Metal-free dihydrogen oxidation by a borenium cation: a combined electrochemical/frustrated Lewis pair approach.

7. Metal-free electrocatalytic hydrogen oxidation using frustrated Lewis pairs and carbon-based Lewis acids.

8. Using Ylide Functionalization to Stabilize Boron Cations.

9. N-Heterocycle-Ligated Borocations as Highly Tunable Carbon Lewis Acids.

Review 10. From CO₂ activation to catalytic reduction: a metal-free approach.

Review 10. From CO2 activation to catalytic reduction: a metal-free approach.

Review 10. From CO₂ activation to catalytic reduction: a metal-free approach.