Literature DB >> 22914808

Plutonium(IV) complexation by diglycolamide ligands--coordination chemistry insight into TODGA-based actinide separations.

Sean D Reilly1, Andrew J Gaunt, Brian L Scott, Giuseppe Modolo, Mudassir Iqbal, Willem Verboom, Mark J Sarsfield.   

Abstract

Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1 : 3 homoleptic Pu(IV) complex with the nitrate anions forced into the outer coordination sphere.

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Year:  2012        PMID： 22914808     DOI： 10.1039/c2cc34967a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Formation and Fragmentation Chemistry of Tripositive Ln(TMGA)33+ Complexes in the Gas Phase.

Authors:  Xiuting Chen; Qingnuan Li; Yu Gong
Journal:  J Am Soc Mass Spectrom       Date:  2017-05-02       Impact factor: 3.109

2.  Formation and Characterization of Zr4+ Stabilized by Neutral Tridentate Ligands in the Gas Phase.

Authors:  Xiuting Chen; Qingnuan Li; Yu Gong
Journal:  J Am Soc Mass Spectrom       Date:  2018-08-23       Impact factor: 3.109

3.  Outer-Sphere Water Clusters Tune the Lanthanide Selectivity of Diglycolamides.

Authors:  Anna G Baldwin; Alexander S Ivanov; Neil J Williams; Ross J Ellis; Bruce A Moyer; Vyacheslav S Bryantsev; Jenifer C Shafer
Journal:  ACS Cent Sci       Date:  2018-06-14       Impact factor: 14.553

4.  Prediction of Binding Stability of Pu(IV) and PuO2(VI) by Nitrogen Tridentate Ligands in Aqueous Solution.

Authors:  Keunhong Jeong; Hye Jin Jeong; Seung Min Woo; Sungchul Bae
Journal:  Int J Mol Sci       Date:  2020-04-17       Impact factor: 5.923

5.  Understanding Selectivity of Mesoporous Silica-Grafted Diglycolamide-Type Ligands in the Solid-Phase Extraction of Rare Earths.

Authors:  Justyna Florek; Dominic Larivière; Hanspeter Kählig; Sonia L Fiorilli; Barbara Onida; Frédéric-Georges Fontaine; Freddy Kleitz
Journal:  ACS Appl Mater Interfaces       Date:  2020-12-10       Impact factor: 9.229
  5 in total

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