Literature DB >> 22901039

Rhodium-catalyzed asymmetric coupling reaction of allylic ethers with arylboronic acids.

Hiroyoshi Kiuchi1, Dai Takahashi, Kenji Funaki, Tetsuo Sato, Shuichi Oi.   

Abstract

An asymmetric allylic substitution of simple allylic ethers with arylboronic acids in the presence of a rhodium(I)/(R)-DTBM-SEGPHOS catalyst has been developed. The reactions proceeded smoothly at room temperature to give the corresponding branch products with excellent regioselectivities and good to excellent enantioselectivities.

Entities:  

Year:  2012        PMID: 22901039     DOI: 10.1021/ol3019902

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

Review 1.  Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C Bonds.

Authors:  Alan H Cherney; Nathaniel T Kadunce; Sarah E Reisman
Journal:  Chem Rev       Date:  2015-08-13       Impact factor: 60.622

2.  Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates.

Authors:  Philipp Schäfer; Thomas Palacin; Mireia Sidera; Stephen P Fletcher
Journal:  Nat Commun       Date:  2017-06-13       Impact factor: 14.919

  2 in total

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