| Literature DB >> 22900890 |
Jun-ichi Nishigaki1, Risako Tsunoyama, Hironori Tsunoyama, Nobuyuki Ichikuni, Seiji Yamazoe, Yuichi Negishi, Mikinao Ito, Tsukasa Matsuo, Kohei Tamao, Tatsuya Tsukuda.
Abstract
A gold cluster, Au(41)(S-Eind)(12), was synthesized by ligating the bulky arenethiol 1,1,3,3,5,5,7,7-octaethyl-s-hydrindacene-4-thiol (Eind-SH) to preformed Au clusters. Extended X-ray absorption fine structure, X-ray photoelectron spectroscopy, and the fragmentation pattern in the mass spectrometry analysis indicated that formation of gold-thiolate oligomers at the interface was suppressed, in sharp contrast to conventional thiolate-protected Au clusters.Entities:
Year: 2012 PMID： 22900890 DOI： 10.1021/ja305477a
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419