Literature DB >> 22887748

Hunting for the magnesium(I) species: formation, structure, and reactivity of some donor-free Grignard compounds.

Tomasz Kruczyński1, Nikolay Pushkarevsky, Patrick Henke, Ralf Köppe, Elke Baum, Sergey Konchenko, Jerzy Pikies, Hansgeorg Schnöckel.   

Abstract

Magnesium bromide radicals have to be prepared as high-temperature molecules and trapped as a metastable solution because a seemingly simple reduction of donor-free Grignard compounds failed. However, the essential role of magnesium(I) species during the formation of Grignard compounds could be demonstrated experimentally.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 22887748     DOI： 10.1002/anie.201204997

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  Bis(η(5)-penta-methyl-cyclo-penta-dien-yl)aluminium tetra-bromido-aluminate.

Authors:  Andrew P Purdy; Cherrelle Dugger; Ray J Butcher
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-02-08

2.  Many Mg-Mg bonds form the core of the Mg16Cp*8Br4K cluster anion: the key to a reassessment of the Grignard reagent (GR) formation process?

Authors:  T Kruczyński; F Henke; M Neumaier; K H Bowen; H Schnöckel
Journal:  Chem Sci       Date:  2015-11-26       Impact factor: 9.825

3.  Access to a Labile Monomeric Magnesium Radical by Ball-Milling.

Authors:  Dawid Jędrzkiewicz; Jonathan Mai; Jens Langer; Zachary Mathe; Neha Patel; Serena DeBeer; Sjoerd Harder
Journal:  Angew Chem Int Ed Engl       Date:  2022-02-18       Impact factor: 16.823
  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.