Literature DB >> 22855457

Ligand-accelerated activation of strong C-H bonds of alkanes by a (salen)ruthenium(VI)-nitrido complex.

Wai-Lun Man1, William W Y Lam, Hoi-Ki Kwong, Shek-Man Yiu, Tai-Chu Lau.   

Abstract

Kinetic and mechanistic studies on the intermolecular activation of strong C-H bonds of alkanes by a (salen)ruthenium(VI) nitride were performed. The initial, rate-limiting step, the hydrogen atom transfer (HAT) from the alkane to Ru(VI)≡N, generates Ru(V)=NH and RC·HCH(2)R. The following steps involve N-rebound and desaturation.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 22855457     DOI： 10.1002/anie.201204136

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  Theoretical and experimental studies of phenol oxidation by ruthenium complex with N,N,N-tris(benzimidazol-2yl-methyl)amine.

Authors:  J Guadalupe Hernandez; Antonio Romero Silva; Pandiyan Thangarasu; Rafael Herrera Najera; Alfonso Duran Moreno; M Teresa Orta Ledesma; Julian Cruz-Borbolla; Narinder Singh
Journal:  J Mol Model       Date:  2015-08-08       Impact factor: 1.810

2.  Reaction of an iron(IV) nitrido complex with cyclohexadienes: cycloaddition and hydrogen-atom abstraction.

Authors:  Wei-Tsung Lee; Ruth A Juarez; Jeremiah J Scepaniak; Salvador B Muñoz; Diane A Dickie; Haobin Wang; Jeremy M Smith
Journal:  Inorg Chem       Date:  2014-07-28       Impact factor: 5.165

3.  Nitrogen Atom Transfer Catalysis by Metallonitrene C-H Insertion: Photocatalytic Amidation of Aldehydes.

Authors:  Till Schmidt-Räntsch; Hendrik Verplancke; Jonas N Lienert; Serhiy Demeshko; Matthias Otte; Gerard P Van Trieste; Kaleb A Reid; Joseph H Reibenspies; David C Powers; Max C Holthausen; Sven Schneider
Journal:  Angew Chem Int Ed Engl       Date:  2022-01-14       Impact factor: 16.823
  3 in total

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