Literature DB >> 22854184

The synthesis of 2-deoxy-α-D-glycosides from D-glycals catalyzed by TMSI and PPh3.

Xi-Kai Cui1, Ming Zhong, Xiang-Bao Meng, Zhong-Jun Li.   

Abstract

2-Deoxyglycosides were synthesized in high α-selectivity by the direct addition of alcohols to D-glucal and D-galactal catalyzed by TMSI and PPh(3). The acid labile isopropylidene group is tolerated under this condition.
Copyright © 2012 Elsevier Ltd. All rights reserved.

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Year:  2012        PMID: 22854184     DOI: 10.1016/j.carres.2012.06.004

Source DB:  PubMed          Journal:  Carbohydr Res        ISSN: 0008-6215            Impact factor:   2.104


  2 in total

1.  TMSBr-mediated solvent- and work-up-free synthesis of α-2-deoxyglycosides from glycals.

Authors:  Mei-Yuan Hsu; Yi-Pei Liu; Sarah Lam; Su-Ching Lin; Cheng-Chung Wang
Journal:  Beilstein J Org Chem       Date:  2016-08-04       Impact factor: 2.883

2.  Cooperative Brønsted Acid-Type Organocatalysis for the Stereoselective Synthesis of Deoxyglycosides.

Authors:  Carlos Palo-Nieto; Abhijit Sau; Ryan Williams; M Carmen Galan
Journal:  J Org Chem       Date:  2016-12-22       Impact factor: 4.354

  2 in total

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