| Literature DB >> 22834487 |
Enrique E Maroto1, Salvatore Filippone, Angel Martín-Domenech, Margarita Suarez, Nazario Martín.
Abstract
Stereodivergent syntheses of cis/trans pyrrolidino[3,4:1,2]fullerenes and endo/exo pyrrolidines are reported with high enantioselectivity levels. Fullerenes are revealed as a useful benchmark to develop suitable catalysts to control the stereochemical outcome and to shed light on the mechanism involved in the related 1,3-dipolar cycloaddition.Entities:
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Year: 2012 PMID: 22834487 DOI: 10.1021/ja306105b
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419