Literature DB >> 22831386

Biomass conversion to high value chemicals: from furfural to chiral hydrofuroins in two steps.

Anzhelika Kabro1, Eduardo C Escudero-Adán, Vladimir V Grushin, Piet W N M van Leeuwen.   

Abstract

Catalytic asymmetric transfer hydrogenation of rac-furoin and furil produces hydrofuroin with up to 99% ee and 9:1 dr. This reaction provides an exceptionally easy access to optically active hydrofuroins in two straightforward steps from biomass-derived furfural (global production 200,000-300,000 t annually) using benzoin condensation.

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Year:  2012        PMID: 22831386     DOI: 10.1021/ol3018402

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Organocatalytic upgrading of furfural and 5-hydroxymethyl furfural to C10 and C12 furoins with quantitative yield and atom-efficiency.

Authors:  Hongjun Zang; Eugene Y X Chen
Journal:  Int J Mol Sci       Date:  2015-03-30       Impact factor: 5.923

  1 in total

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