Literature DB >> 22823323

Absolute configurations of unique harziane diterpenes from Trichoderma species.

Feng-Ping Miao1, Xiao-Rui Liang, Xiu-Li Yin, Gang Wang, Nai-Yun Ji.   

Abstract

Harzianone (2), a new harziane diterpene, was isolated from an alga-endophytic isolate of Trichoderma longibrachiatum. The structure and absolute configuration of 2 were unambiguously identified by NMR and mass spectrometric methods as well as quantum chemical calculations. The absolute configuration of harziandione (1) was supported by calculation of optical rotation, and the structure of isoharziandione was revised to 1 on the basis of (13)C NMR data comparison and calculation.

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Year:  2012        PMID： 22823323     DOI： 10.1021/ol3014717

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  12 in total

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