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Literature DB >> 22821885

Catalytic asymmetric Claisen rearrangement of enolphosphonates: construction of vicinal tertiary and all-carbon quaternary centers.

Jiajing Tan¹, Cheol-Hong Cheon, Hisashi Yamamoto.

Abstract

Entities: Chemical

Mesh：

Substances：
Organophosphonates

Year: 2012 PMID： 22821885 PMCID： PMC3517105 DOI： 10.1002/anie.201203092

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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57 in total

1. Pyridine-2,6-bis(oxazolines), helpful ligands for asymmetric catalysts.

Authors: Giovanni Desimoni; Giuseppe Faita; Paolo Quadrelli
Journal: Chem Rev Date: 2003-08 Impact factor: 60.622

2. Acyclic stereocontrol in the Ireland-Claisen rearrangement of alpha-branched esters.

Authors: Ying-chuan Qin; Craig E Stivala; Armen Zakarian
Journal: Angew Chem Int Ed Engl Date: 2007 Impact factor: 15.336

3. Targeting structural and stereochemical complexity by organocascade catalysis: construction of spirocyclic oxindoles having multiple stereocenters.

Authors: Giorgio Bencivenni; Li-Yuan Wu; Andrea Mazzanti; Berardino Giannichi; Fabio Pesciaioli; Mao-Ping Song; Giuseppe Bartoli; Paolo Melchiorre
Journal: Angew Chem Int Ed Engl Date: 2009 Impact factor: 15.336

4. Highly enantioselective conjugate additions to alpha,beta-unsaturated ketones catalyzed by a (salen)Al complex.

Authors: Mark S Taylor; David N Zalatan; Andreas M Lerchner; Eric N Jacobsen
Journal: J Am Chem Soc Date: 2005-02-02 Impact factor: 15.419

5. Enantioselective and diastereoselective Mukaiyama-Michael reactions catalyzed by bis(oxazoline) copper(II) complexes.

Authors: D A Evans; K A Scheidt; J N Johnston; M C Willis
Journal: J Am Chem Soc Date: 2001-05-16 Impact factor: 15.419

6. Enantio- and diastereoselective Michael reaction of 1,3-dicarbonyl compounds to nitroolefins catalyzed by a bifunctional thiourea.

Authors: Tomotaka Okino; Yasutaka Hoashi; Tomihiro Furukawa; Xuenong Xu; Yoshiji Takemoto
Journal: J Am Chem Soc Date: 2005-01-12 Impact factor: 15.419

7. A new copper acetate-bis(oxazoline)-catalyzed, enantioselective Henry reaction.

Authors: David A Evans; Daniel Seidel; Magnus Rueping; Hon Wai Lam; Jared T Shaw; C Wade Downey
Journal: J Am Chem Soc Date: 2003-10-22 Impact factor: 15.419

8. Preparation of asymmetric alpha-ketophosphonates by [3,3]-sigmatropic shift of enolphosphonates.

Authors: Kamyar Afarinkia; Andrew J Twist; Hiu-wan Yu
Journal: J Org Chem Date: 2004-09-17 Impact factor: 4.354

9. Enantioselective Claisen rearrangements with a hydrogen-bond donor catalyst.

Authors: Christopher Uyeda; Eric N Jacobsen
Journal: J Am Chem Soc Date: 2008-06-25 Impact factor: 15.419

10. Catalytic asymmetric rearrangement of allylic trichloroacetimidates. A practical method for preparing allylic amines and congeners of high enantiomeric purity.

Authors: Carolyn E Anderson; Larry E Overman
Journal: J Am Chem Soc Date: 2003-10-15 Impact factor: 15.419

8 in total

1. Gold(I)-Catalyzed Desymmetrization of 1,4-Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement.

Authors: Hongmiao Wu; Weiwei Zi; Guigen Li; Hongjian Lu; F Dean Toste
Journal: Angew Chem Int Ed Engl Date: 2015-06-01 Impact factor: 15.336

2. Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysis.

Authors: Wen-Bo Liu; Corey M Reeves; Scott C Virgil; Brian M Stoltz
Journal: J Am Chem Soc Date: 2013-07-12 Impact factor: 15.419

Catalytic asymmetric Claisen rearrangement of enolphosphonates: construction of vicinal tertiary and all-carbon quaternary centers.

1. Pyridine-2,6-bis(oxazolines), helpful ligands for asymmetric catalysts.

2. Acyclic stereocontrol in the Ireland-Claisen rearrangement of alpha-branched esters.

3. Targeting structural and stereochemical complexity by organocascade catalysis: construction of spirocyclic oxindoles having multiple stereocenters.

4. Highly enantioselective conjugate additions to alpha,beta-unsaturated ketones catalyzed by a (salen)Al complex.

5. Enantioselective and diastereoselective Mukaiyama-Michael reactions catalyzed by bis(oxazoline) copper(II) complexes.

6. Enantio- and diastereoselective Michael reaction of 1,3-dicarbonyl compounds to nitroolefins catalyzed by a bifunctional thiourea.

7. A new copper acetate-bis(oxazoline)-catalyzed, enantioselective Henry reaction.

8. Preparation of asymmetric alpha-ketophosphonates by [3,3]-sigmatropic shift of enolphosphonates.

9. Enantioselective Claisen rearrangements with a hydrogen-bond donor catalyst.

10. Catalytic asymmetric rearrangement of allylic trichloroacetimidates. A practical method for preparing allylic amines and congeners of high enantiomeric purity.

1. Gold(I)-Catalyzed Desymmetrization of 1,4-Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement.

2. Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysis.

3. Congested C-C bonds by Pd-catalyzed enantioselective allyl-allyl cross-coupling, a mechanism-guided solution.

4. Carbanion-accelerated Claisen rearrangements: asymmetric induction with chiral phosphorus-stabilized anions.

5. Enantioselective Allenoate-Claisen Rearrangement Using Chiral Phosphate Catalysts.

6. Enantio-, diastereo-, and regioselective iridium-catalyzed asymmetric allylic alkylation of acyclic β-ketoesters.

7. Ten years of research in Chicago.

8. Stereodivergent synthesis of vicinal quaternary-quaternary stereocenters and bioactive hyperolactones.