Literature DB >> 22810960

Iodine activation of coordinated white phosphorus: formation and transformation of 1,3-dihydride-2-iodidecyclotetraphosphane.

Pierluigi Barbaro1, Carla Bazzicalupi, Maurizio Peruzzini, Stefano Seniori Costantini, Piero Stoppioni.   

Abstract

Double stabilization: Previously unknown polyphosphorus compounds are obtained by activation of white phosphorus (P(4)) coordinated between two CpRu(PPh(3))(2) moieties with iodine, and subsequent hydrolysis. The polyphosphorus compounds (P(4) H(2) I, P(4) H(2), P(3) H(5); see scheme, Cp=cyclopentadienyl) are all stabilized by coordination to two ruthenium centers.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 22810960     DOI： 10.1002/anie.201203908

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  8 in total

1.  Activation of white phosphorus by low-valent group 5 complexes: formation and reactivity of cyclo-P4 inverted sandwich compounds.

Authors:  Clément Camp; Laurent Maron; Robert G Bergman; John Arnold
Journal:  J Am Chem Soc       Date:  2014-12-03       Impact factor: 15.419

2.  Metalate-Mediated Functionalization of P4 by Trapping Anionic [Cp*Fe(CO)2(η1-P4)]- with Lewis Acids.

Authors:  Jaap E Borger; Maarten K Jongkind; Andreas W Ehlers; Martin Lutz; J Chris Slootweg; Koop Lammertsma
Journal:  ChemistryOpen       Date:  2017-03-23       Impact factor: 2.911

Review 3.  Functionalization of Pentaphosphorus Cations by Complexation.

Authors:  Anup K Adhikari; Christoph G P Ziegler; Kai Schwedtmann; Clemens Taube; Jan J Weigand; Robert Wolf
Journal:  Angew Chem Int Ed Engl       Date:  2019-11-06       Impact factor: 15.336

4.  [3+2] Fragmentation of a Pentaphosphido Ligand by Cyanide.

Authors:  Christian M Hoidn; Thomas M Maier; Karolina Trabitsch; Jan J Weigand; Robert Wolf
Journal:  Angew Chem Int Ed Engl       Date:  2019-11-07       Impact factor: 15.336

Review 5.  Transition-Metal-Mediated Functionalization of White Phosphorus.

Authors:  Christian M Hoidn; Daniel J Scott; Robert Wolf
Journal:  Chemistry       Date:  2020-11-18       Impact factor: 5.236

6.  Halogenation and Nucleophilic Quenching: Two Routes to E-X Bond Formation in Cobalt Triple-Decker Complexes (E=As, P; X=F, Cl, Br, I).

Authors:  Anna Garbagnati; Martin Piesch; Michael Seidl; Gábor Balázs; Manfred Scheer
Journal:  Chemistry       Date:  2022-06-14       Impact factor: 5.020

7.  Halogenation of the Hexaphosphabenzene Complex [(Cp*Mo)2 (μ,η6 :η6 -P6 )]: Snapshots on the Reaction Progress.

Authors:  Anna Garbagnati; Michael Seidl; Gábor Balázs; Manfred Scheer
Journal:  Chemistry       Date:  2022-04-21       Impact factor: 5.020

8.  Construction of alkyl-substituted pentaphosphido ligands in the coordination sphere of cobalt.

Authors:  Christoph G P Ziegler; Thomas M Maier; Stefan Pelties; Clemens Taube; Felix Hennersdorf; Andreas W Ehlers; Jan J Weigand; Robert Wolf
Journal:  Chem Sci       Date:  2018-12-04       Impact factor: 9.825
  8 in total

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