Di-μ-bromido-bis-[benz-yl(diethyl ether)magnesium].

The title benzyl Grignard reagent, [Mg(2)Br(2)(C(7)H(7))(2)(C(4)H(10)O)(2)], was obtained by reaction of benzyl bromide with magnesium in diethyl ether, followed by crystallization from toluene. The asymmetric unit comprises one half-mol-ecule, the structural dimeric unit being generated by inversion symmetry with an Mg⋯Mg distance of 3.469 (2) Å. The Mg(II) atom exhibits a distorted tetrahedral coordination geometry. The crystal packing is defined by van der Waals inter-actions only.

Related literature

For the structures of some other diethyl ether adducts of Grignard reagents, see: Stucky & Rundle (1964 ▶); Guggenberger & Rundle (1968 ▶); Engelhardt et al. (1988 ▶); Antolini et al. (2003 ▶); Avent et al. (2004 ▶). For the structures of some tetra­hydro­furan and diisopropyl ether adducts of Grignard reagents, see: Maurice (1969 ▶); Spek et al. (1974 ▶); Krieck et al. (2009 ▶).

Experimental

Crystal data

[Mg2Br2(C7H7)2(C4H10O)2]

M = 538.93

Monoclinic,

a = 8.0657 (4) Å

b = 12.4288 (6) Å

c = 13.1840 (6) Å

β = 96.370 (3)°

V = 1313.50 (11) Å3

Z = 2

Mo Kα radiation

μ = 3.15 mm−1

T = 193 K

0.38 × 0.27 × 0.23 mm

Data collection

Bruker Platform APEXII CCD diffractometer

Absorption correction: integration (SADABS; Bruker, 2007 ▶) T min = 0.440, T max = 0.635

22801 measured reflections

2396 independent reflections

1808 reflections with I > 2σ(I)

R int = 0.078

Refinement

R[F 2 > 2σ(F 2)] = 0.031

wR(F 2) = 0.073

S = 1.04

2396 reflections

129 parameters

H-atom parameters not refined

Δρmax = 0.42 e Å−3

Δρmin = −0.36 e Å−3

Data collection: APEX2 (Bruker, 2010 ▶); cell refinement: SAINT (Bruker, 2005 ▶); data reduction: SAINT and XPREP (Bruker, 2005 ▶); program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL ▶; software used to prepare material for publication: XCIF (Bruker, 2005 ▶).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536812025445/kp2423sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536812025445/kp2423Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Mg2Br2(C7H7)2(C4H10O)2]	F(000) = 552
Mr = 538.93	Dx = 1.363 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 5006 reflections
a = 8.0657 (4) Å	θ = 2.3–23.5°
b = 12.4288 (6) Å	µ = 3.15 mm−1
c = 13.1840 (6) Å	T = 193 K
β = 96.370 (3)°	Prism, colourless
V = 1313.50 (11) Å3	0.38 × 0.27 × 0.23 mm
Z = 2

Bruker Platform APEXII CCD diffractometer	2396 independent reflections
Radiation source: normal-focus sealed tube	1808 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.078
profile data from φ and ω scans	θmax = 25.3°, θmin = 2.3°
Absorption correction: integration (SADABS; Bruker, 2007)	h = −9→9
Tmin = 0.440, Tmax = 0.635	k = −14→14
22801 measured reflections	l = −15→15

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.031	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.073	H-atom parameters not refined
S = 1.04	w = 1/[σ2(Fo2) + (0.0305P)2 + 0.0177P] where P = (Fo2 + 2Fc2)/3
2396 reflections	(Δ/σ)max = 0.001
129 parameters	Δρmax = 0.42 e Å−3
0 restraints	Δρmin = −0.36 e Å−3

Experimental. One distinct cell was identified using APEX2 (Bruker, 2010). Ten frame series were integrated and filtered for statistical outliers using SAINT (Bruker, 2005) then corrected for absorption by integration using SHELXTL/XPREP V2005/2 (Bruker, 2005) before using SADABS (Bruker, 2005) to sort, merge, and scale the combined data. No decay correction was applied.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. The structure was phased by direct methods (Sheldrick, 2008). The systematic conditions suggested the unambiguous space group. The space group choice was confirmed by successful convergence of the full-matrix least-squares refinement on F2. The highest peaks in the final difference Fourier map were in the vicinity of atom Br1; the final map had no other significant features. A final analysis of variance between observed and calculated structure factors showed little dependence on amplitude or resolution.

	x	y	z	Uiso*/Ueq
Mg1	1.18152 (11)	0.47556 (7)	0.08013 (7)	0.0396 (2)
Br1	0.89572 (3)	0.55206 (2)	0.11052 (2)	0.05037 (13)
O1	1.1776 (2)	0.32859 (13)	0.14171 (14)	0.0459 (5)
C1	1.3770 (3)	0.6793 (2)	0.0998 (2)	0.0396 (7)
C2	1.4242 (4)	0.7119 (2)	0.0058 (2)	0.0521 (8)
H2	1.4702	0.6604	−0.0364	0.063*
C3	1.4058 (4)	0.8173 (3)	−0.0276 (3)	0.0655 (10)
H3	1.4394	0.8370	−0.0919	0.079*
C4	1.3403 (4)	0.8927 (3)	0.0310 (3)	0.0712 (10)
H4	1.3288	0.9651	0.0080	0.085*
C5	1.2908 (4)	0.8638 (2)	0.1233 (3)	0.0624 (9)
H5	1.2448	0.9164	0.1644	0.075*
C6	1.3072 (3)	0.7593 (2)	0.1567 (2)	0.0488 (7)
H6	1.2702	0.7407	0.2203	0.059*
C7	1.3934 (3)	0.56671 (19)	0.1365 (2)	0.0468 (7)
H7A	1.4057	0.5658	0.2120	0.056*
H7B	1.4947	0.5340	0.1134	0.056*
C8	1.0390 (4)	0.2534 (2)	0.1235 (2)	0.0545 (8)
H8A	0.9597	0.2804	0.0665	0.065*
H8B	0.9794	0.2499	0.1852	0.065*
C9	1.0940 (4)	0.1444 (2)	0.0986 (2)	0.0708 (10)
H9A	0.9964	0.0977	0.0838	0.106*
H9B	1.1665	0.1153	0.1567	0.106*
H9C	1.1557	0.1477	0.0387	0.106*
C10	1.2862 (4)	0.3105 (2)	0.2361 (2)	0.0547 (8)
H10A	1.3958	0.3446	0.2307	0.066*
H10B	1.3047	0.2322	0.2457	0.066*
C11	1.2145 (4)	0.3549 (3)	0.3267 (2)	0.0777 (10)
H11A	1.2928	0.3431	0.3880	0.117*
H11B	1.1088	0.3187	0.3345	0.117*
H11C	1.1948	0.4323	0.3173	0.117*

	U11	U22	U33	U12	U13	U23
Mg1	0.0341 (5)	0.0340 (5)	0.0493 (6)	0.0000 (4)	−0.0015 (4)	0.0023 (4)
Br1	0.0424 (2)	0.0587 (2)	0.0502 (2)	0.00999 (14)	0.00602 (14)	−0.00680 (14)
O1	0.0356 (11)	0.0375 (10)	0.0617 (12)	−0.0040 (8)	−0.0073 (9)	0.0111 (9)
C1	0.0255 (16)	0.0405 (16)	0.0514 (18)	−0.0041 (12)	−0.0023 (13)	−0.0063 (13)
C2	0.0464 (19)	0.0541 (19)	0.056 (2)	−0.0063 (15)	0.0071 (16)	−0.0068 (15)
C3	0.059 (2)	0.069 (2)	0.069 (2)	−0.0160 (18)	0.0071 (19)	0.0179 (18)
C4	0.059 (2)	0.042 (2)	0.109 (3)	−0.0042 (17)	−0.005 (2)	0.015 (2)
C5	0.050 (2)	0.0429 (19)	0.093 (3)	0.0043 (16)	0.0063 (19)	−0.0131 (18)
C6	0.0376 (18)	0.0501 (18)	0.0593 (19)	−0.0034 (14)	0.0081 (15)	−0.0048 (14)
C7	0.0356 (17)	0.0392 (16)	0.064 (2)	−0.0012 (13)	−0.0001 (14)	0.0002 (13)
C8	0.0441 (18)	0.0441 (17)	0.074 (2)	−0.0092 (15)	0.0004 (16)	0.0044 (15)
C9	0.093 (3)	0.0498 (19)	0.068 (2)	−0.0076 (19)	0.001 (2)	−0.0049 (16)
C10	0.0472 (19)	0.0471 (18)	0.065 (2)	0.0049 (14)	−0.0134 (17)	0.0164 (15)
C11	0.087 (3)	0.085 (3)	0.060 (2)	0.004 (2)	0.002 (2)	0.0078 (19)

Mg1—O1	2.0006 (18)	C5—C6	1.373 (4)
Mg1—C7	2.115 (3)	C5—H5	0.9500
Mg1—Br1i	2.5448 (9)	C6—H6	0.9500
Mg1—Br1	2.5659 (9)	C7—H7A	0.9900
Mg1—Mg1i	3.4690 (17)	C7—H7B	0.9900
Br1—Mg1i	2.5448 (9)	C8—C9	1.474 (4)
O1—C8	1.456 (3)	C8—H8A	0.9900
O1—C10	1.458 (3)	C8—H8B	0.9900
C1—C2	1.396 (4)	C9—H9A	0.9800
C1—C6	1.401 (3)	C9—H9B	0.9800
C1—C7	1.482 (3)	C9—H9C	0.9800
C2—C3	1.385 (4)	C10—C11	1.490 (4)
C2—H2	0.9500	C10—H10A	0.9900
C3—C4	1.358 (4)	C10—H10B	0.9900
C3—H3	0.9500	C11—H11A	0.9800
C4—C5	1.371 (4)	C11—H11B	0.9800
C4—H4	0.9500	C11—H11C	0.9800
O1—Mg1—C7	113.26 (9)	C1—C6—H6	119.0
O1—Mg1—Br1i	105.34 (6)	C1—C7—Mg1	110.56 (17)
C7—Mg1—Br1i	121.26 (9)	C1—C7—H7A	109.5
O1—Mg1—Br1	102.71 (6)	Mg1—C7—H7A	109.5
C7—Mg1—Br1	116.84 (8)	C1—C7—H7B	109.5
Br1i—Mg1—Br1	94.50 (3)	Mg1—C7—H7B	109.5
O1—Mg1—Mg1i	110.90 (6)	H7A—C7—H7B	108.1
C7—Mg1—Mg1i	135.62 (8)	O1—C8—C9	112.5 (3)
Br1i—Mg1—Mg1i	47.51 (2)	O1—C8—H8A	109.1
Br1—Mg1—Mg1i	47.00 (2)	C9—C8—H8A	109.1
Mg1i—Br1—Mg1	85.50 (3)	O1—C8—H8B	109.1
C8—O1—C10	114.8 (2)	C9—C8—H8B	109.1
C8—O1—Mg1	124.43 (16)	H8A—C8—H8B	107.8
C10—O1—Mg1	116.89 (15)	C8—C9—H9A	109.5
C2—C1—C6	115.8 (3)	C8—C9—H9B	109.5
C2—C1—C7	122.7 (3)	H9A—C9—H9B	109.5
C6—C1—C7	121.5 (3)	C8—C9—H9C	109.5
C3—C2—C1	121.7 (3)	H9A—C9—H9C	109.5
C3—C2—H2	119.1	H9B—C9—H9C	109.5
C1—C2—H2	119.1	O1—C10—C11	112.2 (2)
C4—C3—C2	120.5 (3)	O1—C10—H10A	109.2
C4—C3—H3	119.7	C11—C10—H10A	109.2
C2—C3—H3	119.7	O1—C10—H10B	109.2
C3—C4—C5	119.6 (3)	C11—C10—H10B	109.2
C3—C4—H4	120.2	H10A—C10—H10B	107.9
C5—C4—H4	120.2	C10—C11—H11A	109.5
C4—C5—C6	120.3 (3)	C10—C11—H11B	109.5
C4—C5—H5	119.8	H11A—C11—H11B	109.5
C6—C5—H5	119.8	C10—C11—H11C	109.5
C5—C6—C1	122.0 (3)	H11A—C11—H11C	109.5
C5—C6—H6	119.0	H11B—C11—H11C	109.5

Table 1

Selected bond lengths (Å)

Mg1—O1	2.0006 (18)
Mg1—C7	2.115 (3)
Mg1—Br1i	2.5448 (9)
Mg1—Br1	2.5659 (9)

Symmetry code: (i) .