Literature DB >> 22806772

A (31) P NMR investigation of the CoPi water-oxidation catalyst.

Stephen J Harley1, Harris E Mason, J Gregory McAlpin, R David Britt, William H Casey.   

Abstract

Beneath the sheets: (31) P NMR data suggests that phosphates are liberated freely in the interlayer of a cobalt-hydroxide water-oxidation catalyst. The cobalt-hydroxide sheets are separated by an interlayer region with water, counterions and phosphate, which help to shuttle protons as the layer develops charge.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID: 22806772     DOI: 10.1002/chem.201201292

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  1 in total

1.  Oxyanion induced variations in domain structure for amorphous cobalt oxide oxygen evolving catalysts, resolved by X-ray pair distribution function analysis.

Authors:  Gihan Kwon; Oleksandr Kokhan; Ali Han; Karena W Chapman; Peter J Chupas; Pingwu Du; David M Tiede
Journal:  Acta Crystallogr B Struct Sci Cryst Eng Mater       Date:  2015-12-01
  1 in total

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