Literature DB >> 22801589

Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene.

Takahiro Sasamori1, Michiyasu Sakagami, Masatoshi Niwa, Heisuke Sakai, Yukio Furukawa, Norihiro Tokitoh.   

Abstract

The synthesis and characterization of a stable 1,2-bis(ferrocenyl)diphosphene, wherein a P=P π-bond connects two ferrocenyl units will be reported. This represents an unprecedented example for a d-π electron system containing a heavier pnictogen π-spacer group. Stabilization of the highly reactive P=P π-bond was achieved by steric protection using two bulky ferrocenyl moieties.

Entities:  

Year:  2012        PMID： 22801589     DOI： 10.1039/c2cc33277a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts.

Authors:  Ulysse Caniparoli; Imma Escofet; Antonio M Echavarren
Journal:  ACS Catal       Date:  2022-02-25       Impact factor: 13.084

2.  Stepwise reduction of a base-stabilised ferrocenyl aluminium(iii) dihalide for the synthesis of structurally-diverse dialane species.

Authors:  Debabrata Dhara; Felipe Fantuzzi; Marcel Härterich; Rian D Dewhurst; Ivo Krummenacher; Merle Arrowsmith; Conor Pranckevicius; Holger Braunschweig
Journal:  Chem Sci       Date:  2022-08-01       Impact factor: 9.969

3.  Synthesis of Polysubstituted Ferrocenesulfoxides.

Authors:  Min Wen; William Erb; Florence Mongin; Yury S Halauko; Oleg A Ivashkevich; Vadim E Matulis; Thierry Roisnel
Journal:  Molecules       Date:  2022-03-09       Impact factor: 4.411

4.  Chalcogen-Transfer Rearrangement: Exploring Inter- versus Intramolecular P-P Bond Activation.

Authors:  Roman Franz; Sina Nasemann; Clemens Bruhn; Zsolt Kelemen; Rudolf Pietschnig
Journal:  Chemistry       Date:  2020-11-09       Impact factor: 5.020
  4 in total

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