Literature DB >> 22791418

Two zeolite-type frameworks in one metal-organic framework with Zn24 @Zn104 cube-in-sodalite architecture.

Fei Bu1, Qipu Lin, Quanguo Zhai, Le Wang, Tao Wu, Shou-Tian Zheng, Xianhui Bu, Pingyun Feng.   

Abstract

Two in one: A metal-organic framework obtained from three different inorganic building blocks (tetrameric Zn(4) O, trimeric Zn(3) OH, and monomeric Zn) posseses a nested cage-in-cage and framework-in-framework architecture. 24 Zn(4) O tetramers and eight Zn monomers form a sodalite cage into which a cubic cage made from eight Zn(3) (OH) trimers is nestled. Eight monomeric Zn(2+) centers interconnect these two cages.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID: 22791418     DOI: 10.1002/anie.201203425

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  2 in total

1.  Cholesterol removal by selected metal-organic frameworks as adsorbents.

Authors:  Emin Yilmaz; Ezgi Şenel; Selçuk Ok
Journal:  J Food Sci Technol       Date:  2019-08-26       Impact factor: 2.701

2.  Enhancing the stability and porosity of penetrated metal-organic frameworks through the insertion of coordination sites.

Authors:  Rui Feng; Yan-Yuan Jia; Zhao-Yang Li; Ze Chang; Xian-He Bu
Journal:  Chem Sci       Date:  2017-11-15       Impact factor: 9.825

  2 in total

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