Literature DB >> 22775770

Regioselective double hydrophosphination of terminal arylacetylenes catalyzed by an iron complex.

Masahiro Kamitani1, Masumi Itazaki, Chihiro Tamiya, Hiroshi Nakazawa.   

Abstract

The first catalytic double hydrophosphination of alkynes was achieved by reaction with diarylphosphines in the presence of an iron catalyst. The double hydrophosphination proceeded regioselectively and effectively for various secondary arylphosphines and terminal alkynes to give 1,2-bisphosphinoethane derivatives.

Entities:  

Year:  2012        PMID： 22775770     DOI： 10.1021/ja304818c

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  2 in total

1.  Synthesis and Characterization of Phosphinecarboxamide and Phosphinecarbothioamide, and Their Complexation with Palladium(II) Complex.

Authors:  Masumi Itazaki; Kento Okabayashi; Takanari Matsutani; Tomoya Nochida; Toshiyuki Moriuchi; Hiroshi Nakazawa
Journal:  Molecules       Date:  2022-08-29       Impact factor: 4.927

Review 2.  Broken Promises? On the Continued Challenges Faced in Catalytic Hydrophosphination.

Authors:  Samantha Lau; Thomas M Hood; Ruth L Webster
Journal:  ACS Catal       Date:  2022-08-22       Impact factor: 13.700
  2 in total

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